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a, \(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
b, \(n_{C_2H_4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(n_{CO_2}=2n_{C_2H_4}=0,4\left(mol\right)\Rightarrow m_{CO_2}=0,4.44=17,6\left(g\right)\)
c, \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
\(n_{CaCO_3}=n_{CO_2}=0,4\left(mol\right)\Rightarrow m_{CaCO_3}=0,4.100=40\left(g\right)\)
a, PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
Ta có: \(n_{CH_4}+n_{C_2H_4}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\left(1\right)\)
Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,2\left(mol\right)\\n_{C_2H_4}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,2.22,4}{6,72}.100\%\approx66,67\%\\\%V_{C_2H_4}\approx33,33\%\end{matrix}\right.\)
b, Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=0,7\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,7.22,4=15,68\left(l\right)\)
\(n_{C_2H_4} = \dfrac{44,8}{22,4} = 2(mol)\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ n_{O_2} = 3n_{C_2H_4} = 6(mol)\\ m_{O_2} = 6.32 = 192(gam)\)
\(n_{Mg}=\dfrac{m}{M}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ PTHH:2Mg+O_2\underrightarrow{t^o}2MgO\\ \left(mol\right)-0,2--0,1--0,2\\ V_{O_2}=n.22,4=0,1.22,4=2,24\left(l\right)\)
a)
n CO2 = 6,6/44 = 0,15(mol) => n C = n CO2 = 0,15(mol)
n H2O = 5,4/18 = 0,3(mol) => n H = 2n H2O = 0,6(mol)
=> n O = (4,8 - 0,15.12 - 0,6)/16 = 0,15(mol)
Ta có :
n C : n H : n O = 0,15: 0,6 : 0,15 = 1 : 4 : 1
=> CTP của A là (CH4O)n
M A = (12 + 4 + 16)n = 3,2/(2,24/22,4) = 32
=> n = 1
Vậy CTPT của A là CH4O
b)
$2CH_3OH + 2Na \to 2CH_3ONa + H_2$
n CH3OH = n CO2 = 0,15(mol)
=> n H2 = 1/2 n CH3OH = 0,075(mol)
=> V H2 = 0,075.22,4 = 1,68(lít)
\(n_{C_2H_5OH}=\dfrac{23}{46}=0,5\left(mol\right)\\a, PTHH:C_2H_5OH+3O_2\rightarrow\left(t^o\right)2CO_2+3H_2O\\ b,n_{O_2}=3.0,5=1,5\left(mol\right)\\ V_{O_2\left(đktc\right)}=22,4.1,5=33,6\left(l\right)\\ c,V_{C_2H_5OH}=46\%.100=46\left(ml\right)\\ C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\\ n_{C_2H_5OH}=\dfrac{0,8.46}{46}=0,8\left(mol\right)\\ n_{H_2}=\dfrac{0,8}{2}=0,4\left(mol\right)\Rightarrow V_{H_2\left(đktc\right)}=0,4.22,4=8,96\left(l\right)\)
\(4Al+3O_2\underrightarrow{^{to}}2Al_2O_3\\ n_{Al}=\dfrac{0,54}{27}=0,02\left(mol\right)\\ \Rightarrow n_{Al_2O_3}=\dfrac{2}{4}.0,02=0,01\left(mol\right)\\ n_{O_2}=\dfrac{3}{4}.0,02=0,015\left(mol\right)\\ m_{Al_2O_3}=102.0,01=1,02\left(g\right)\\ V_{O_2\left(đktc\right)}=0,015.22,4=0,336\left(l\right)\)