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nAl = 5.4 / 27 = 0.2 (mol)
2Al + 6HCl => 2AlCl3 + 3H2
0.2......0.6............0.2.......0.3
a) VH2 = 0.3 * 22.4 = 6.72 (l)
b) mAlCl3 = 0.2 * 133.5 = 26.7 (g)
c) VddHCl = 0.6 / 1.5 = 0.4 (l)
d) CMAlCl3 = 0.2 / 0.4 = 0.5 (M)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\\V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(l\right)=400\left(ml\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\end{matrix}\right.\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ n_{H_2SO_4}=0,16.5=0,8\left(mol\right)\)
PTHH: 2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
LTL: \(\dfrac{0,2}{2}< \dfrac{0,8}{3}\rightarrow\)H2SO4 dư
Theo pt: \(\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,2=0,3\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2\left(g\right)\\V_{H_2}=0,3.22,4=6,72\left(l\right)\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,2}{5}=0,04M\\C_{M\left(H_2SO_4.dư\right)}=\dfrac{0,8-0,3}{5}=0,1M\end{matrix}\right.\)
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH :
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
0,4 1,2 0,4 0,6
\(a,V_{H_2}=0,6.22,4=13,44\left(l\right)\)
\(b,m_{HCl}=1,2.36,5=43,8\left(g\right)\)
\(c,m_{AlCl_3}=133,5.0,4=53,4\left(g\right)\)
\(m_{ddHCl}=\dfrac{43,8.100}{10}=438\left(g\right)\)
\(m_{ddAlCl_3}=10,8+438-\left(0,6.2\right)=447,6\left(g\right)\)
\(C\%=\dfrac{53,8}{447,6}.100\%\approx12,02\%\)
a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
b, Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
Theo PT: \(\left\{{}\begin{matrix}n_{HCl}=3n_{Al}=0,6\left(mol\right)\\n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{HCl}=0,6.36,5=21,9\left(g\right)\)
\(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
c, Cách 1:
Theo PT: \(n_{AlCl_3}=n_{Al}=0,2\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\)
Cách 2:
Ta có: \(m_{H_2}=0,3.2=0,6\left(g\right)\)
Theo ĐLBT KL, có: mAl + mHCl = mAlCl3 + mH2
⇒ mAlCl3 = mAl + mHCl - mH2 = 5,4 + 21,9 - 0,6 = 26,7 (g)
Bạn tham khảo nhé!
\(n_{H_2SO_4}=0,1.3=0,3\left(mol\right)\)
PT: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
Theo PT: \(n_{Zn}=n_{H_2SO_4}=0,3\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Theo PT: \(n_{ZnCl_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
Bài 1:
\(n_{H_2SO_4}=\dfrac{300.19,6\%}{98}=0,6\left(mol\right);n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Vì:\dfrac{0,1}{2}< \dfrac{0,6}{3}\Rightarrow H_2SO_4dư\\ n_{Al_2\left(SO_4\right)_3}=\dfrac{3n_{Al}}{2}=\dfrac{3.0,1}{2}=0,15\left(mol\right)\\ a,m_{Al_2\left(SO_4\right)_3}=342.0,15=51,3\left(g\right)\\ b,m_{ddsau}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=2,7+300-\dfrac{3}{2}.0,1.2=302,4\left(g\right)\\ c,C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{51,3}{302,4}.100\%\approx16,964\%\\ n_{H_2SO_4\left(dư\right)}=0,6-\dfrac{3}{2}.0,1=0,45\left(mol\right)\\ C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{0,45.98}{302,4}.100\%\approx14,583\%\)
Bài 2:
\(PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Mg}=b\left(mol\right)\left(a,b>0\right)\\ Hpt:\left\{{}\begin{matrix}27a+24b=7,8\\1,5a+b=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ \%m_{Al}=\dfrac{0,2.27}{7,8}.100\%\approx69,231\%\Rightarrow\%m_{Mg}\approx100\%-69,231\%\approx30,769\%\)
Theo gt ta có: $n_{Al}=0,1(mol)$
a, $2Al+6HCl\rightarrow 2AlCl_3+3H_2$
b, $\Rightarrow n_{H_2}=0,15(mol)\Rightarrow V_{H_2}=3,36(l)$
c, Ta có: $n_{HCl}=0,3(mol)\Rightarrow m_{HCl}=10,95(g)\Rightarrow \%m_{ddHCl}=219(g)$
d, Bảo toàn khối lượng ta có: $m_{dd}=221,4(g)$
$\Rightarrow \%C_{AlCl_3}=6,02\%$
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{FeCl_2}=n_{H_2}=n_{Fe}=0,15\left(mol\right)\\ n_{HCl}=0,15.2=0,3\left(mol\right)\\ a,m_{FeCl_2}=127.0,15=19,05\left(g\right)\\ b,V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ c,C_{MddHCl}=\dfrac{0,3}{0,02}=15\left(M\right)\)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
Ta có: \(n_{HCl}=0,2.0,3=0,06\left(mol\right)\)
a, Theo PT: \(n_{Al}=\dfrac{1}{3}n_{HCl}=0,02\left(mol\right)\)
\(\Rightarrow m_{Al}=0,02.27=0,54\left(g\right)\)
b, Theo PT: \(n_{AlCl_3}=\dfrac{1}{3}n_{Al}=0,02\left(mol\right)\)
\(\Rightarrow C_{M_{AlCl_3}}=\dfrac{0,02}{0,2}=0,1\left(M\right)\)