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a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Ta có: \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,2.24,79=4,958\left(l\right)\)
b, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\Rightarrow V_{HCl}=\dfrac{0,4}{2}=0,2\left(l\right)\)
c, \(C_{M_{ZnCl_2}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
PT: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
a, Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,2}{1}\). ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)
b, Ta có: \(m_{ZnSO_4}=0,1.161=16,1\left(g\right)\)
c, \(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,1}{0,2}=0,5M\)
\(C_{M_{ZnSO_4}}=\dfrac{0,1}{0,2}=0,5M\)
Bạn tham khảo nhé!
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,2\left(mol\right)\\n_{FeCl_2}=0,1\left(mol\right)=n_{H_2}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,1\cdot22,4=2,24\left(l\right)\\m_{FeCl_2}=0,1\cdot127=12,7\left(g\right)\\C_{M_{FeCl_2}}=\dfrac{0,1}{0,1}=1\left(M\right)\\C_{M_{HCl}}=\dfrac{0,2}{0,1}=2\left(M\right)\end{matrix}\right.\)
a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, \(n_{Fe}=\dfrac{1,12}{56}=0,02\left(mol\right)\)
\(n_{H_2SO_4}=0,2.0,12=0,024\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,02}{1}< \dfrac{0,024}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{FeSO_4}=n_{Fe}=0,02\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,024-0,02=0,004\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{FeSO_4}}=\dfrac{0,02}{0,2}=0,1\left(M\right)\\C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,004}{0,2}=0,02\left(M\right)\end{matrix}\right.\)
\(a) n_{Fe_2O_3}= \dfrac{8}{160} = 0,05(mol)\\ Fe_2O_3 + 6HCl \to 2FeCl_3 + 3H_2O\\ n_{FeCl_3} = 2n_{Fe_2O_3} = 0,1(mol)\\ m_{FeCl_3} = 0,1.162,5 = 16,25(gam)\\ b) n_{HCl} = 6n_{Fe_2O_3} = 0,05.6 = 0,3(mol)\\ V_{dd\ HCl} = \dfrac{0,3}{0,5} = 0,6(lít)\\ c) V_{dd\ sau\ pư} = V_{dd\ HCl} =0,6(lít)\\ C_{M_{FeCl_3}} = \dfrac{0,1}{0,6} = 0,167M\)
PTHH:\(Fe_2O_3+HCl\rightarrow FeCl_3+3H_2O\)
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
a, Bảo toàn nguyên tố Fe:
\(n_{FeCl_3}=n_{Fe}=2n_{Fe_2O_3}=2.0,05=0,1\left(mol\right)\)
\(\Rightarrow m_{FeCl_3}=162,5.0,1=16,25\left(g\right)\)
b, Bảo toàn nguyên tố Cl:
\(n_{Hcl}=n_{Cl}=3n_{FeCl_3}=3.0,1=0,3\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{n_{HCL}}{C_M}=\dfrac{0,3}{0,5}=0,6\left(l\right)\)
c,\(C_{M_{FeCl_3}}=\dfrac{n_{FeCl_3}}{V_{ddFeCl_3}}=\dfrac{0,1}{0,6}=0,17M\)
nFe = 0,1 mol
nHCl = 0,3 mol
Fe + 2HCl ---> FeCl2 + H2
0,1 < 0,3/2 .....=> HCl dư sau phản ứng
nFeCl2 = 0,1 mol => CM = 0,1/0,2 = 0,5M
nHCl(dư) = 0,1 mol => CM = 0,1/0,2 = 0,5M
a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
b) Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\\n_{HCl}=0,2\cdot1,5=0,3\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,3}{2}\) \(\Rightarrow\) Fe p/ứ hết, HCl còn dư
\(\Rightarrow n_{HCl\left(dư\right)}=0,1\left(mol\right)\) \(\Rightarrow m_{HCl\left(dư\right)}=0,1\cdot36,5=3,65\left(g\right)\)
c) Theo PTHH: \(n_{FeCl_2}=n_{Fe}=0,1\left(mol\right)=n_{HCl\left(dư\right)}\)
\(\Rightarrow C_{M_{FeCl_2}}=C_{M_{HCl\left(dư\right)}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)
nHCl=0,6 mol
FeO+2HCl-->FeCl2+ H2O
x mol x mol
Fe2O3+6HCl-->2FeCl3+3H2O
x mol 2x mol
72x+160x=11,6 =>x=0,05 mol
A/ CFeCl2=0,05/0,3=1/6 M
CFeCl3=0,1/0,3=1/3 M
CHCl du=(0,6-0,4)/0,3=2/3 M
B/
NaOH+ HCl-->NaCl+H2O
0,2 0,2
2NaOH+FeCl2-->2NaCl+Fe(OH)2
0,1 0,05
3NaOH+FeCl3-->3NaCl+Fe(OH)3
0,3 0,1
nNaOH=0,6
CNaOH=0,6/1,5=0,4M
\(n_{Ca}=\dfrac{8}{40}=0,2\left(mol\right)\)
\(n_{HCl}=C_M.V=2.0,4=0,8\left(mol\right)\)
PTHH :
\(Ca+2HCl\rightarrow CaCl_2+H_2\)
Trc p/u : 0,2 0,8
p/u 0,2 0,4 0,2 0,2
Sau p/u 0 0,4 0,2 0,2
-> Sau p/ư HCl dư
\(m_{H_2}=0,2.2=0,4\left(g\right)\)
\(C_{M_{CaCl_2}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)
\(n_{Ca}=\dfrac{8}{40}=0,2\left(mol\right)\\ n_{HCl}=0,4.2=0,8\left(mol\right)\\ PTHH:Ca+2HCl\rightarrow CaCl_2+H_2\\ Vì:\dfrac{0,2}{1}< \dfrac{0,8}{2}\Rightarrow HCldư\\ n_{CaCl_2}=n_{Ca}=0,2\left(mol\right);n_{HCl\left(dư\right)}=0,8-0,2.2=0,4\left(mol\right)\\ V_{ddsau}=V_{ddHCl}=0,4\left(l\right)\\ C_{MddCaCl_2}=\dfrac{0,2}{0,4}=0,5\left(M\right);C_{MddHCl\left(dư\right)}=\dfrac{0,4}{0,4}=1\left(M\right)\)