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nHCl=0,6 mol
FeO+2HCl-->FeCl2+ H2O
x mol x mol
Fe2O3+6HCl-->2FeCl3+3H2O
x mol 2x mol
72x+160x=11,6 =>x=0,05 mol
A/ CFeCl2=0,05/0,3=1/6 M
CFeCl3=0,1/0,3=1/3 M
CHCl du=(0,6-0,4)/0,3=2/3 M
B/
NaOH+ HCl-->NaCl+H2O
0,2 0,2
2NaOH+FeCl2-->2NaCl+Fe(OH)2
0,1 0,05
3NaOH+FeCl3-->3NaCl+Fe(OH)3
0,3 0,1
nNaOH=0,6
CNaOH=0,6/1,5=0,4M
a)
\(n_{H_2\left(1\right)}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: 2Na + 2H2O --> 2NaOH + H2 (1)
0,6<----------------------0,3
=> mNa = 0,6.23 = 13,8 (g)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,1<-0,2
=> mFe = 0,1.56 = 5,6 (g)
mCu = 10 (g)
\(\left\{{}\begin{matrix}\%Na=\dfrac{13,8}{13,8+5,6+10}.100\%=46,94\%\\\%Fe=\dfrac{5,6}{13,8+5,6+10}.100\%=19,05\%\\\%Cu=\dfrac{10}{13,8+5,6+10}.100\%=34,01\%\end{matrix}\right.\)
b)
PTHH: FexOy + yH2 --to--> xFe + yH2O
\(\dfrac{0,3}{y}\)<--0,3
=> \(M_{Fe_xO_y}=\dfrac{17,4}{\dfrac{0,3}{y}}=58y\left(g/mol\right)\)
=> 56x = 42y
=> \(\dfrac{x}{y}=\dfrac{3}{4}\) => CTHH: Fe3O4
a)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: 2Na + 2H2O --> 2NaOH + H2
0,6<----------------------0,3
Fe + 2HCl --> FeCl2 + H2
0,1<--0,2
=> \(\left\{{}\begin{matrix}m_{Na}=0,6.23=13,8\left(g\right)\\m_{Fe}=0,1.56=5,6\left(g\right)\\m_{Cu}=10\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%m_{Na}=\dfrac{13,8}{13,8+5,6+10}.100\%=46,94\%\\\%m_{Fe}=\dfrac{5,6}{13,8+5,6+10}.100\%=19,05\%\\\%m_{Cu}=\dfrac{10}{13,8+5,6+10}.100\%=34,01\%\end{matrix}\right.\)
b)
PTHH: FexOy + yH2 --to--> xFe + yH2O
\(\dfrac{0,3}{y}\)<--0,3
=> \(M_{Fe_xO_y}=56x+16y=\dfrac{17,4}{\dfrac{0,3}{y}}\left(g/mol\right)\)
=> \(\dfrac{x}{y}=\dfrac{3}{4}\)
=> CTHH: Fe3O4
a)
\(Zn + 2HCl \to ZnCl_2 + H_2\\ Fe_2O_3 + 6HCl \to 2FeCl_3 + 3H_2\)
Theo PTHH : \(n_{Zn} = n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)\)
\(\Rightarrow n_{Fe_2O_3} = \dfrac{35,5-0,3.65}{160} = 0,1\\ \Rightarrow n_{HCl} = 2n_{Zn} + 6n_{Fe_2O_3} = 0,3.2 + 0,1.6 = 1,2(mol)\\ \Rightarrow m_{HCl} = 1,2.36,5 = 43,8(gam)\)
b)
\(CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O\)
Gọi \(n_{CuO} = a;n_{Fe_2O_3} = b\)
\(\left\{{}\begin{matrix}80a+160b=19,6\\a+3b=0,3\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a=0,135\\b=0,055\end{matrix}\right.\)
Vậy :
\(\left\{{}\begin{matrix}n_{Cu}=0,135\\n_{Fe}=0,055.2=0,11\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{Cu}=0,135.64=8,64\left(gam\right)\\m_{Fe}=0,11.56=6,16\left(gam\right)\end{matrix}\right.\)
a)
$Fe +H_2SO_4 \to FeSO_4 + H_2$
$FeSO_4 + 2KOH \to Fe(OH)_2 + K_2SO_4$
$4Fe(OH)_2 + O_2 \xrightarrow{t^o} 2Fe_2O_3 + 4H_2O$
$n_{Fe_2O_3} = \dfrac{20}{160} = 0,125(mol)$
Theo PTHH : $n_{Fe} = 2n_{Fe_2O_3} = 0,25(mol)$
$m_{Fe} = 0,25.56 = 14(gam)$
b)
$n_{H_2} = n_{Fe} = 0,25(mol)$
$V_{H_2} = 0,25.22,4 = 5,6(lít)$
c)
$n_{H_2SO_4} = n_{Fe} = 0,25(mol)$
$V_{dd\ H_2SO_4} = \dfrac{0,25}{1} = 0,25(lít) = 250(ml)$
\(PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ FeSO_4+2KOH\rightarrow Fe\left(OH\right)_2+K_2SO_4\\4 Fe\left(OH\right)_2+O_2\underrightarrow{t^o}2Fe_2O_3+4H_2O\)
\(a.n_{Fe_2O_3}=\dfrac{20}{160}=0,125\left(mol\right)\\ n_{H_2}=n_{H_2SO_4}=n_{Fe}=n_{FeSO_4}=n_{Fe\left(OH\right)_2}=\dfrac{4}{2}.0,125=0,25\left(mol\right)\\ m_{Fe}=0,25.56=14\left(g\right)\\ b.V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\\ c.V_{ddH_2SO_4}=\dfrac{0,25}{1}=0,25\left(l\right)=250\left(ml\right)\)