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a. PTHH: \(CuSO_4+2NaOH--->Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
b. Đổi 100ml = 0,1 lít
Ta có: \(n_{Cu\left(OH\right)_2}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
Theo PT: \(n_{CuSO_4}=n_{Cu\left(OH\right)_2}=0,1\left(mol\right)\)
=> \(m_{CuSO_4}=0,1.160=16\left(g\right)\)
c. Theo PT: \(n_{NaOH}=2.n_{CuSO_4}=2.0,1=0,2\left(mol\right)\)
=> \(C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2M\)
a) $CuSO_4 + 2NaOH \to Cu(OH)_2 + Na_2SO_4$
b) $n_{Cu(OH)_2} = n_{CuSO_4} = \dfrac{16}{160} = 0,1(mol)$
$m_{Cu(OH)_2} = 0,1.98 = 9,8(gam)$
c) $n_{NaOH} = 2n_{CuSO_4} = 0,2(mol) \Rightarrow C_{M_{NaOH}} = \dfrac{0,2}{0,1} = 2M$
PTHH: \(CuSO_4+2NaOH\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
Ta có: \(n_{CuSO_4}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{NaOH}=0,2\left(mol\right)\\n_{Cu\left(OH\right)_2}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2\left(M\right)\\m_{Cu\left(OH\right)_2}=0,1\cdot98=9,8\left(g\right)\end{matrix}\right.\)
\(n_{CuSO_4}=\dfrac{200.16\%}{160}=0,2\left(mol\right)\)
PTHH :
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)
0,2 0,4 0,2 0,2
\(m_{NaOH}=0,4.40=16\left(g\right)\)
\(m_{ddNaOH}=\dfrac{16.100}{10}=160\left(g\right)\)
\(c,m_{Na_2SO_4}=0,2.142=28,4\left(g\right)\)
\(m_{ddNa_2SO_4}=200+160-\left(0,2.98\right)=340,4\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{28,4}{240,4}.100\%\approx8,34\%\)
\(d,PTHH:\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
0,2 0,2
\(m_{CuO}=0,2.80=16\left(g\right)\)
a, \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
b, \(m_{CuSO_4}=200.16\%=32\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{32}{160}=0,2\left(mol\right)\)
\(n_{NaOH}=2n_{CuSO_4}=0,4\left(mol\right)\Rightarrow m_{ddNaOH}=\dfrac{0,4.40}{10\%}=160\left(g\right)\)
c, \(n_{Cu\left(OH\right)_2}=n_{Na_2SO_4}=n_{CuSO_4}=0,2\left(mol\right)\)
\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,2.142}{200+160-0,2.98}.100\%\approx8,34\%\)
d, \(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)
c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)
a) PTHH: \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\)
\(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)
b) Ta có: \(n_{FeCl_3}=0,3\cdot0,5=0,15\left(mol\right)\)
\(\Rightarrow n_{NaOH}=0,45mol\) \(\Rightarrow V_{ddNaOH}=\dfrac{0,45}{0,25}=1,8\left(l\right)\)
c) Theo PTHH: \(n_{NaCl}=n_{NaOH}=0,45mol\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,45}{2,1}\approx0,21\left(M\right)\)
(Coi như thể tích dd thay đổi không đáng kể)
d) Theo PTHH: \(n_{H_2SO_4}=\dfrac{3}{2}n_{Fe\left(OH\right)_3}=\dfrac{3}{2}n_{FeCl_3}=0,225mol\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,225\cdot98}{20\%}=110,25\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{110,25}{1,14}\approx96,71\left(ml\right)\)
\(3NaOH+FeCl_3\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(n_{NaCl}=n_{NaOH}=0,2.3=0,6\left(mol\right)\)
=> \(C_{M\left(NaCl\right)}=\dfrac{0,6}{0,2}=3M\)
\(n_{Fe\left(ỌH\right)_3}=\dfrac{1}{3}n_{NaOH}=0,2\left(mol\right)\)
\(2Fe\left(OH\right)_3-^{t^o}\rightarrow Fe_2O_3+3H_2O\)
Ta có \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,1\left(mol\right)\)
=> m Fe2O3 = 0,1 . 160=16(g)
a, \(n_{Cu\left(OH\right)_2}=\dfrac{0,49}{98}=0,005\left(mol\right)\)
Chất kết tủa là Cu(OH)2
PTHH: 2NaOH + CuSO4 → Na2SO4 + Cu(OH)2 ↓
Mol: 0,01 0,005
b, \(C_{M_{ddNaOH}}=\dfrac{0,01}{0,02}=0,5M\)
\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
Kết tủa thu được: \(Cu\left(OH\right)_2\downarrow\)
\(n_{Cu\left(OH\right)_2}=\dfrac{0,49}{98}=0,005mol\)
\(\Rightarrow n_{NaOH}=2n_{Cu\left(OH\right)_2}=2\cdot0,005=0,01mol\)
\(C_M=\dfrac{0,01}{\dfrac{20}{1000}}=0,5M\)