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a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{H_2}=0,4\left(mol\right)\Rightarrow V_{HCl}=\dfrac{0,4}{2}=0,2\left(l\right)\)
\(n_{ZnCl_2}=n_{H_2}=0,2\left(mol\right)\Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
\(n_{H_2}=\dfrac{2,479}{22,4}=\dfrac{2479}{22400}mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Theo pt ta có: \(n_{Zn}=n_{H_2}=\dfrac{2479}{22400}mol\)\(\approx0,11mol\)
\(\Rightarrow m_{Zn}\approx7,2g\)
\(n_{HCl}=2n_{H_2}=0,22mol\) \(\Rightarrow C_{M_{HCl}}=\dfrac{0,22}{0,1}=2,2M\)
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
\(n_{BaCl_2}=\dfrac{31,2}{208}=0,15mol\)
\(BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\)
0,15 0,15 0,15 0,3
a)\(m_{BaSO_4}=0,15\cdot233=34,95\left(g\right)\)
b)\(m_{H_2SO_4}=0,15\cdot98=14,7\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{14,7}{19,6}\cdot100=75\left(g\right)\)
c)\(m_{HCl}=0,3\cdot36,5=10,95\left(g\right)\)
\(m_{ddsau}=31,2+75-34,95=71,25\left(g\right)\)
\(\Rightarrow C\%_{HCl}=\dfrac{10,95}{71,25}\cdot100\%=15,37\%\)
\(n_{NaOH}=\dfrac{100.8%}{100\%.40}=0,2(mol)\\ n_{FeCl_2}=\dfrac{254.10\%}{100\%.127}=0,2(mol)\\ PTHH:2NaOH+FeCl_2\to Fe(OH)_2\downarrow +2NaCl\)
Vì \(\dfrac{n_{NaOH}}{2}<\dfrac{n_{FeCl_2}}{1}\) nên \(FeCl_2\) dư
\(\Rightarrow n_{Fe(OH)_2}=\dfrac{1}{2}n_{NaOH}=0,1(mol);n_{NaCl}=0,2(mol)\\ \Rightarrow m_{Fe(OH)_2}=0,1.90=9(g);m_{NaCl}=0,2.58,5=11,7(g)\\ b,C\%_{NaCl}=\dfrac{11,7}{100+254-9}.100\%=3,39\%\)
PTPU
Zn+ 2HCl\(\rightarrow\) ZnCl2+ H2\(\uparrow\)
0,1.................0,1.............. mol
ta có: nZn= \(\dfrac{6,5}{65}\)= 0,1( mol)
\(\Rightarrow\) mZnCl2= 0,1. 136= 13,6( g)
Ta có: \(n_{ZnO}=\dfrac{16,2}{81}=0,2\left(mol\right)\)
a, PT: \(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
______0,2_____0,4____0,2 (mol)
b, \(m_{HCl}=0,4.36,5=14,6\left(g\right)\Rightarrow m_{ddHCl}=\dfrac{14,6}{10\%}=146\left(g\right)\)
c, \(C\%_{ZnCl_2}=\dfrac{0,2.136}{16,2+146}.100\%\approx16,77\%\)
Bạn tham khảo nhé!