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n Zn= 19,5/65=0,3 (mol).
PTPƯ: Zn(0.3) + HCl(0.6) ----> ZnCl2(0.3) + H2(0,3)
mHCl=0,6.36.5=21.9(g)
a) C%HCl= 21.9/300.100%=7,3%
b) VH2=0,3.22,4=6,72(lít)
c) mH2=0,3.2=0,6(g)
mZnCl2=0,3.136=40,8(g)
mddZnCl2 =(19,5+300)-0,6=318,9(g)
C%=mZnCl2/mddZnCl2.100= 40,8/318,9.100=12,793%
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,4 0,8 0,4 0,4
\(a,V_{H_2}=0,4.22,4=8,96\left(l\right)\\ b,C\%_{HCl}=\dfrac{0,8.36,5}{150}.100\%=19,5\%\\ c,m_{\text{dd}}=26+150-\left(0,4.2\right)=175,2\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,4.136}{175,2}.100\%=31\%\)
nZn = 19,5 / 65 = 0,3 (mol)
Zn + 2HCl -->ZnCl2 + H2
0,3 0,6 0,3 0,3 (mol)
VH2 =0,3.22,4 = 6,72 (l)
V = 200ml = 0,2 (l)
CMHCl = n/V = 0,6 / 0,2 = 3M
\(n_{Zn}=\dfrac{65}{65}=1\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
1 1 1
\(b,V_{H_2}=1.22,4=22,4\left(l\right)\)
\(c,m_{ZnCl_2}=1.136=136\left(g\right)\)
\(m_{ddZnCl_2}=65+\left(\dfrac{2.36,5:15}{100}\right)-2\approx549,67\left(g\right)\)
\(C\%_{ZnCl_2}=\dfrac{136}{549,67}.100\%\approx24,74\left(\%\right)\)
\(d,H_2+CuO\underrightarrow{t^o}Cu+H_2O\)
trc p/u 1 0,1875
p/u : 0,1875 0,1875 0,1875
sau: 0,8125 0 0,1875
\(n_{CuO}=\dfrac{15}{80}=0,1875\left(mol\right)\)
\(m_{Cu}=0,1875.64=12\left(g\right)\)
`a)PTHH:`
`Zn + 2HCl -> ZnCl_2 + H_2`
`0,1` `0,2` `0,1` `0,1` `(mol)`
`n_[HCl]=0,2.1=0,2(mol)`
`=>m_[Zn]=0,1.65=6,5(g)`
`b)m_[dd HCl]=1,1.200=220(g)`
`=>C%_[ZnCl_2]=[0,1.136]/[6,5+220-0,1.2].100~~6%`
\(a,n_{HCl}=0,2.1=0,2\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,1<--0,2------>0,1------->0,1
\(\rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)
\(b,m_{ddHCl}=200.1,1=220\left(g\right)\)
\(\rightarrow m_{dd}=220+6,5-0,1.2=226,3\left(g\right)\\ \rightarrow C\%_{ZnCl_2}=\dfrac{0,1.136}{226,3}.100\%=6\%\)
\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)
\(n_{HCl}=\dfrac{100\cdot14.6\%}{36.5}=0.4\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(1........2\)
\(0.1......0.4\)
\(LTL:\dfrac{0.1}{1}< \dfrac{0.4}{2}\Rightarrow HCldư\)
\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=6.5+100-0.1\cdot2=106.3\left(g\right)\)
\(C\%ZnCl_2=\dfrac{0.1\cdot136}{106.3}\cdot100\%=12.79\%\)
\(C\%HCl\left(dư\right)=\dfrac{\left(0.4-0.2\right)\cdot36.5}{106.3}\cdot100\%=6.87\%\%\)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,4 0,2
\(V_{H_2}=0,2.22,4=4,48\left(l\right)\\ C\%_{HCl}=\dfrac{0,4.36,5}{200}.100\%=7,3\%\)