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a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\) (1)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\) (2)
b) Ta có: \(\Sigma n_{H_2}=\dfrac{3,024}{22,4}=0,135\left(mol\right)\)
Gọi số mol của Fe là \(a\) \(\Rightarrow n_{H_2\left(1\right)}=a\)
Gọi số mol của Al là \(b\) \(\Rightarrow n_{H_2\left(2\right)}=\dfrac{3}{2}b\)
Ta lập được hệ phương trình:
\(\left\{{}\begin{matrix}a+\dfrac{3}{2}b=0,135\\56b+27b=4,14\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,045\\b=0,06\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,045\cdot56=2,52\left(g\right)\\m_{Al}=1,62\left(g\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{2,52}{4,14}\cdot100\%\approx60,87\%\\\%m_{Al}=39,13\%\end{matrix}\right.\)
c) PTHH: \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\downarrow\)
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3\downarrow+3NaCl\)
\(4Fe\left(OH\right)_2+O_2\underrightarrow{t^o}2Fe_2O_3+4H_2O\)
\(2Al\left(OH\right)_3\underrightarrow{t^o}Al_2O_3+3H_2O\)
Theo các PTHH: \(\left\{{}\begin{matrix}n_{Fe\left(OH\right)_2}=n_{FeCl_2}=0,045mol\\n_{Al\left(OH\right)_3}=n_{AlCl_3}=0,06mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=0,0225mol\\n_{Al_2O_3}=0,03mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2O_3}=0,0225\cdot160=3,6\left(g\right)\\m_{Al_2O_3}=0,03\cdot102=3,06\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{chấtrắn}=3,06+3,6=6,66\left(g\right)\)
a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\)
⇒ mFeO = 12,6 - 5,4 = 7,2 (g)
c, Phần này đề cho dd NaOH dư hay vừa đủ bạn nhỉ?
d, Cho hh vào dd H2SO4 đặc nguội thì có khí thoát ra.
PT: \(2FeO+4H_2SO_{4\left(đ\right)}\rightarrow Fe_2\left(SO_4\right)_3+SO_2+4H_2O\)
Ta có: \(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)
Theo PT: \(n_{SO_2}=\dfrac{1}{2}n_{FeO}=0,05\left(mol\right)\)
\(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,3\left(mol\right)=n_{ZnCl_2}\\n_{HCl}=0,6\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0.3\cdot65}{35,5}\cdot100\%\approx54,93\%\\\%m_{Cu}=45,07\%\\C\%_{HCl}=\dfrac{0,6\cdot36,5}{500}\cdot100\%=4,38\%\\m_{ZnCl_2}=0,3\cdot136=40,8\left(g\right)\end{matrix}\right.\)
Mặt khác: \(\left\{{}\begin{matrix}m_{Cu}=35,5-0,3\cdot65=16\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{dd}=m_{KL}+m_{ddHCl}-m_{Cu}-m_{H_2}=518,9\left(g\right)\)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{40,8}{518,9}\cdot100\%\approx7,86\%\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\)
a)\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,1 0,1
\(m_{Fe}=0,1\cdot56=5,6\left(g\right)\)
b)\(\Rightarrow\%m_{Fe}=\dfrac{5,6}{12}\cdot100\%=46,67\%\) \(\Rightarrow\%m_{Cu}=100\%-46,67\%=53,33\%\)
c)\(n_{NaOH}=0,1\cdot1=0,1mol\)
\(2NaOH+FeCl_2\rightarrow Fe\left(OH\right)_2+2NaCl\)
0,1 0,1 0,1
\(m_{Fe\left(OH\right)_2}=0,1\cdot90=9\left(g\right)\)
cảm ơn ạ