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Sửa đề : 11.2 g sắt
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(0.2....0.2.................0.2\)
\(m_{FeSO_4}=0.2\cdot152=30.4\left(g\right)\)
\(C_{M_{H_2SO_4}}=\dfrac{0.2}{0.05}=4\left(M\right)\)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right);n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\\ PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Vì:\dfrac{0,4}{1}>\dfrac{0,25}{1}\Rightarrow Fe.dư\\ n_{H_2}=n_{Fe\left(p.ứ\right)}=n_{H_2SO_4}=0,25\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\\ b,n_{Fe\left(dư\right)}=0,4-0,25=0,15\left(g\right)\\ m_{Fe\left(dư\right)}=0,14.56=8,4\left(g\right)\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2mol\)
\(n_{HCl}=2,5.0,2=0,5mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,2 < 0,5 ( mol )
0,2 0,4 0,2 0,2 ( mol )
Chất dư là HCl
\(m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65g\)
\(V_{H_2}=0,2.22,4=4,48l\)
\(C_{M_{FeCl_2}}=\dfrac{0,2}{0,2}=1M\)
a)
\(Mg + H_2SO_4 \to MgSO_4 + H_2\\ n_{H_2} = n_{Mg} = \dfrac{3,6}{24} = 0,15(mol)\\ b)\\ CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ n_{Cu} = n_{H_2} = 0,15(mol)\\ \Rightarrow m_{Cu} = 0,15.64 = 9,6(gam)\)
a) Fe + H2SO4 --> FeSO4 + H2
b) \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + H2SO4 --> FeSO4 + H2
0,1------------------------>0,1
=> VH2 = 0,1.22,4 = 2,24 (l)
c) \(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
Xét tỉ lệ: \(\dfrac{0,15}{1}>\dfrac{0,1}{1}\) => CuO dư, H2 hết
PTHH: CuO + H2 --to--> Cu + H2O
0,1<--0,1------->0,1
=> mCuO(dư) = (0,15 - 0,1).80 = 4 (g)
mCu = 0,1.64 = 6,4 (g)
a, PT: \(Fe+H_2SO_4\rightarrow H_2SO_4+H_2\)
b, Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Fe}=0,1\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c, Ta có: \(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{1}>\dfrac{0,1}{1}\), ta được CuO dư.
Theo PT: \(n_{Cu}=n_{CuO\left(pư\right)}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow n_{CuO\left(dư\right)}=0,05\left(mol\right)\Rightarrow m_{CuO\left(dư\right)}=0,05.80=4\left(g\right)\)
\(m_{Cu}=0,1.64=6,4\left(g\right)\)
Bạn tham khảo nhé!
\(nMg=\dfrac{12}{24}=0,5\left(mol\right)\)
\(nH_2SO_4=\dfrac{29,4}{98}=0,3\left(mol\right)\)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
1 1 1 1 (mol)
0,3 0,3 0,3 0,3 (mol)
LTL : 0,5/1 > 0,3/1
=> Mg dư , H2SO4 đủ
\(VH_2=0,3.22,4=6,72\left(l\right)\)
m muối là mMgSO4
=> \(m\left(muối\right)=mMgSO_4=0,3.120=36\left(g\right)\)
\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\
n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,125 0,125 (mol )
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\
\)
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
Bài 18:
Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)
\(m_{H_2}=0,125.2=0,25\left(g\right)\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)
Có: m dd sau pư = 8,125 + 100 - 0,25 = 107,875 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)
Bạn tham khảo nhé!
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\\n_{H_2SO_4}=\dfrac{980\cdot10\%}{98}=1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Axit còn dư, Kẽm p/ứ hết
\(\Rightarrow n_{H_2}=0,4\left(mol\right)\) \(\Rightarrow V_{H_2}=0,4\cdot22,4=8,96\left(l\right)\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\ n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\\ pthh:Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(LTL:\dfrac{0,2}{1}< \dfrac{0,25}{1}\)
=> H2SO4 dư
\(n_{H_2}=n_{H_2SO_4\left(p\text{ư}\right)}=n_{Fe}=0,2\left(mol\right)\\ V_{H_2}=0,2.22,4=4,48l\\ m_{H_2SO_4\left(d\right)}=\left(0,25-0,2\right).98=4,9g\)
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