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a)
Gọi số mol Fe, Al, Ag trong mỗi phần là a, b,c (mol)
=> 56a + 27b + 108c = 5,19 (1)
Phần 1:
\(n_{H_2}=\dfrac{2,352}{22,4}=0,105\left(mol\right)\)
PTHH: Fe + H2SO4 --> FeSO4 + H2
a----->a------------------>a
2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
b------>1,5b------------------->1,5b
=> a + 1,5b = 0,105 (2)
Phần 2:
\(n_{SO_2}=\dfrac{2,912}{22,4}=0,13\left(mol\right)\)
PTHH: 2Al + 6H2SO4 --> Al2(SO4)3 + 3SO2 + 6H2O
b----->3b-------------------->1,5b
2Fe + 6H2SO4 --> Fe2(SO4)3 + 3SO2 + 6H2O
a------>3a--------------------->1,5a
2Ag + 2H2SO4 --> Ag2SO4 + SO2 + 2H2O
c-------->c------------------>0,5c
=> 1,5a + 1,5b + 0,5c = 0,13 (3)
(1)(2)(3) => a = 0,03 (mol); b = 0,05 (mol); c = 0,02 (mol)
=> \(\left\{{}\begin{matrix}m_{Fe}=2.0,03.56=3,36\left(g\right)\\m_{Al}=2.0,05.27=2,7\left(g\right)\\m_{Ag}=2.0,02.108=4,32\left(g\right)\end{matrix}\right.\)
b)
- Phần 1:
\(n_{H_2SO_4}=a+1,5b=0,105\left(mol\right)\)
- Phần 2:
\(n_{H_2SO_4}=3a+3b+c=0,26\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)
\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)
\(NaOH+Al\left(OH\right)_3\rightarrow NaAlO_2+2H_2O\)
\(4Fe\left(OH\right)_2+O_2\underrightarrow{^{^{t^0}}}2Fe_2O_3+4H_2O\)
Ta có :
\(n_{Fe_2O_3}=\dfrac{16}{160}=0.1\left(mol\right)\)
Dựa vào PTHH ta thấy :
\(n_{Fe}=2\cdot n_{Fe_2O_3}=2\cdot0.1=0.2\left(mol\right)\)
\(m_{Fe}=0.2\cdot56=11.2\left(g\right)\)
\(\Rightarrow m_{Al}=19.3-11.2=8.1\left(g\right)\)
\(\%Al=\dfrac{8.1}{19.3}\cdot100\%=41.96\%\)
mk viết nhầm. HSO là H2SO4. BaCl là BaCl2.
NaCO là Na2CO3 . CO là khí CO2
a) \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
Theo PTHH ta có: \(n_{MgCl_2}=n_{Mg}=0,1\left(mol\right)\)
\(\Rightarrow m_{MgCl_2}=n_{MgCl_2}.M_{MgCl_2}=0,1.95=9,5\left(g\right)\)
b) Theo PTHH ta có: \(n_{H_2}=n_{Mg}=0,1\left(mol\right)\)
\(\Rightarrow V_{H_2}=n_{H_2}.22,4=0,1.22,4=2,24\left(l\right)\)
c) \(2H_2+O_2\rightarrow2H_2O\)
Theo PTHH: \(n_{H_2O}=\dfrac{0,1.2}{2}=0,1\left(mol\right)\)
\(\Rightarrow m_{H_2O}=n_{H_2O}.M_{H_2O}=0,1.18=1,8\left(g\right)\)
a)mMg= 2,4/24=0,1(mol) nMgCl2=0,1.1/1=0,1 (mol) mMgCl2= 0,1.95=9,5(g) b)nH2=0,1.1/1=0,1(mol) v=n.22,4=2,24(lít
Phần 1 :
$m_{Cu} = 0,4(gam)$
Gọi $n_{Fe} = a ; n_{Al} = b \Rightarrow 56a + 27b + 0,4 = 1,5 : 2 = 0,75(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$n_{H_2} = a + 1,5b = \dfrac{896}{1000.22,4} = 0,04(2)$
Từ (1)(2) suy ra a = -0,025 < 0$
$\to$ Sai đề
a)
\(2K+2H_2O\rightarrow2KOH+H_2\)
\(2K+2HCl\rightarrow2KCl+H_2\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(4K+O_2\underrightarrow{t^o}2K_2O\)
\(2Mg+O_2\underrightarrow{t^o}2MgO\)
b)
P1: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: 2K + 2H2O --> 2KOH + H2
0,3<--------------------0,15
=> nK(X) = 0,3.3 = 0,9 (mol)
P2:
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PTHH: 2K + 2HCl --> 2KCl + H2
0,3------------------->0,15
Mg + 2HCl --> MgCl2 + H2
0,25<-------------------0,25
=> nMg(X) = 0,25.3 = 0,75 (mol)
P3:
PTHH: 4K + O2 --to--> 2K2O
0,3------------->0,15
2Mg + O2 --to--> 2MgO
0,25--------------->0,25
=> mAg(P3) = 34,9 - 0,15.94 - 0,25.40 = 10,8 (g)
=> mAg(X) = 10,8.3 = 32,4 (g)
a = mX = 0,9.39 + 0,75.24 + 32,4 = 85,5 (g)