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Bài 1
nBaCl2= 200 *2.6%= 5.2 (g) ; nBaCl2= 5.2/208=0.025(mol)
nH2SO4=49*10%=4.9(g) ; nH2SO4=4.9/98=0.05(mol)
PTHH
..........................H2SO4 + BaCl2 ➞ 2HCl + BaSO4
Trước phản ứng:0.05 : 0.025...................................(mol)
Trong phản ứng:0.025 : 0.025......... : 0.025 : 0.05(mol)
Sau phản ứng : 0.025 : 0 ......... : 0.025 : 0.05 (mol)
a) mBaSO4=0.025*233=5.825(g)
b) mdd sau phản ứng = 49+200-5.825=243.175(g)
C% (H2SO4) = (0.025* 98)/243.175*100%=1.007%
C% (HCl) = (0.05*36.5)/243.175*100%=0.007%
Bài 2:
nHCl= 73 *25%= 18.25 (g) ; nHCl= 18.25/36.5=0.5(mol)
nAgNO3=34*5%=1.7(g) ; nAgNO3=1.7/170=0.01(mol)
PTHH
..........................HCl + AgNO3 ➞ AgCl + 2HNO3
Trước phản ứng:0.5 : 0.01......................................(mol)
Trong phản ứng:0.01 : 0.01.............. : 0.01 : 0.01(mol)
Sau phản ứng : 0.49: 0 ............... : 0.01 : 0.01(mol)
a) mAgCl=0.01*143.5=1.435(g)
b) mdd sau phản ứng = 73+34-1.435=105.565(g)
C% (HNO3) = (0.01* 63)/105.565*100%=0.0059%
C% (HCl) = (0.49*36.5)/105.565*100%=16.94%
a) BaCl2 + Na2SO4 -> BaSO4 + 2NaCl
b) mBaCl2 trong dung dịch là:
mBaCl2=C% x mdd/100= 10,4x200/100=20,8gam
=>n BaCl2=20,8/108=0,1 mol.
BaCl2 + Na2SO4 -> BaSO4 + 2NaCl
0,1.............................->0,1 mol
mBaSO4=0,1 x233=23,3gam
c)dung dịch còn lại là NaCl
Áp dụng đlbt kluong:
mdd=mBaCl2 + mNa2SO4 - mBaSO4= 200g + 400g - 23,3g=576,7g
BaCl2 + Na2SO4 -> BaSO4 + 2NaCl
0,1.............................................->0,2
mNaCl= 0,2 x 58,5=11,7 g
C%NaCl= mNaCl x 100 / mdd = 11,7 x 100 / 576,7 = 2,03%
Chúc bạn học tốt! Thân ái!
\(m_{CuSO_4}=\dfrac{200\cdot32}{100}=64\left(g\right)\)\(\Rightarrow n_{CuSO_4}=\dfrac{64}{160}=0,4mol\)
\(m_{BaCl_2}=\dfrac{200\cdot10,4}{100}=20,8\left(g\right)\)\(\Rightarrow n_{BaCl_2}=\dfrac{20,8}{208}=0,1mol\)
\(CuSO_4+BaCl_2\rightarrow BaSO_4\downarrow+CuCl_2\)
0,4 0,1 0,1 0,1
b)\(m_{BaSO_4}=0,1\cdot233=23,3\left(g\right)\)
c)\(m_{CuCl_2}=0,1\cdot135=13,5\left(g\right)\)
\(\Rightarrow m_{ddsau}=200+200-13,5=386,5\left(g\right)\)
\(\Rightarrow C\%=\dfrac{23,3}{386,5}\cdot100\%=6,028\%\)
a, \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\)
\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)
b, \(n_{FeCl_3}=0,4.2=0,8\left(mol\right)\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=2,4\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{2,4}{0,4+0,2}=4\left(M\right)\)
c, \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=\dfrac{1}{2}n_{FeCl_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{Fe_2O_3}=0,4.160=64\left(g\right)\)
\(n_{FeCl3}=2.0,4=0,8\left(mol\right)\)
PTHH : \(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)
0,8----------------------->0,8----------->2,4
b) \(C_{MNaCl}=\dfrac{2,4}{0,4+0,2}=4M\)
c) \(2Fe\left(OH\right)_3\xrightarrow[]{t^o}Fe_2O_3+3H_2O\)
0,8--------------->0,4
\(\Rightarrow a=m_{Fe2O3}=0,4.160=64\left(g\right)\)
\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)
Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)
\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)
\(a,n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ \Rightarrow n_{HCl}=0,4\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,4\cdot36,5=14,6\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{14,6}{200}\cdot100\%=7,3\%\\ b,n_{H_2}=0,2\left(mol\right)\\ \Rightarrow V_{H_2\left(đkc\right)}=0,2\cdot24,79=4,958\left(l\right)\\ c,m_{H_2}=0,2\cdot2=0,4\left(g\right)\\ n_{FeCl_2}=0,2\left(mol\right)\\ \Rightarrow m_{CT_{FeCl_2}}=0,2\cdot127=25,4\left(g\right)\\ \Rightarrow m_{dd_{FeCl_2}}=11,2+200-0,4=210,8\left(g\right)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{25,4}{210,8}\cdot100\%\approx12,05\%\)
a) \(n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2\left(mol\right)\)
PTHH: Na2CO3 + 2HCl --> 2NaCl + CO2 + H2O
0,2------------------>0,4---->0,2
mdd sau pư = 200 + 21,2 - 0,2.44 = 212,4(g)
=> \(C\%\left(NaCl\right)=\dfrac{0,4.58,5}{212,4}.100\%=11,017\%\)
$PTHH:Na_2CO_3+2HCl\to 2NaCl+H_2O+CO_2\uparrow$
$n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2(mol)$
Theo PT: $n_{NaCl}=n_{CO_2}=0,2(mol)$
$\Rightarrow m_{NaCl}=0,4.58,5=23,4(g);m_{CO_2}=0,2.44=8,8(g)$
$\Rightarrow C\%_{NaCl}=\dfrac{23,4}{21,2+200-8,8}.100\%\approx 11,01\%$
\(n_{Na_2CO_3}=\dfrac{200.0,159}{106}=0,3mol\\ n_{BaCl_2}=\dfrac{200.0,208}{208}=0,2mol\\ a.Na_2CO_3+BaCl_2->2NaCl+BaCO_3\\ n_{Na_2CO_3}:1>n_{BaCl_2}:1\\ m_B=197.0,2=39,4g\\ Na_2CO_3+2HCl->2NaCl+H_2O+CO_2\\ V=\dfrac{2.0,1}{1}=0,2\left(L\right)=200\left(mL\right)\\ b.m_A=200+200-39,4=360,6g\\ C\%_{Na_2CO_3du}=\dfrac{106.0,1}{360,6}.100\%=2,94\%\\ C\%_{NaCl}=\dfrac{58,5.0,4}{360,6}.100\%=6,49\%\)
a)
\(Na_2CO_3+BaCl_2\rightarrow BaCO_3+2NaCl\)
0,2 <---------- 0,2 ------> 0,2 -----> 0,4
\(n_{Na_2CO_3}=\dfrac{200.15,9\%}{100\%}:106=0,3\left(mol\right)\)
\(n_{BaCl_2}=\dfrac{200.20,8\%}{100\%}:208=0,2\left(mol\right)\)
Do \(\dfrac{0,3}{1}>\dfrac{0,2}{1}\) nên \(Na_2CO_3\) dư sau phản ứng.
Dung dịch A: \(n_{Na_2CO_3}=0,3-0,2=0,1\left(mol\right);n_{NaCl}:0,4\left(mol\right)\)
Kết tủa B: \(BaCO_3\)
\(m_B=m_{BaCO_3}=0,2.197=39,4\left(g\right)\)
Dung dịch A td với HCl:
\(Na_2CO_3+2HCl\rightarrow2NaCl+H_2O+CO_2\)
0,1 ---------> 0,2
\(V=V_{HCl}=\dfrac{0,2}{1}=0,2\left(l\right)\)
b)
\(m_{dd}=m_{dd.Na_2CO_3}+m_{dd.BaCl_2}-m_{BaCO_3}=200+200-39,4=360,6\left(g\right)\)
\(C\%_{Na_2CO_3}=\dfrac{0,1.106.100\%}{360,6}=2,94\%\)
\(C\%_{NaCl}=\dfrac{0,4.58,5.100\%}{360,6}=6,49\%\)
$a)PTHH:ZnCl_2+2AgNO_3\to Zn(NO_3)_2+2AgCl\downarrow$
$b)n_{ZnCl_2}=\dfrac{200.13,6\%}{136}=0,2(mol)$
Theo PT: $n_{AgNO_3}=2n_{ZnCl_2}=0,4(mol)$
$\Rightarrow C\%_{AgNO_3}=\dfrac{0,4.170}{200}.100\%=34\%$
$c)$ Theo PT: $n_{AgCl}=0,4(mol);n_{Zn(NO_3)_2}=0,2(mol)$
$\Rightarrow m_{AgCl}=0,4.143,5=57,4(g)$
$m_{Zn(NO_3)_2}=0,2.189=37,8(g)$
$\Rightarrow C\%_{Zn(NO_3)_2}=\dfrac{37,8}{200+200-57,4}.100\%\approx 11,03\%$
a) \(ZnCl_2+2AgNO_3\rightarrow Zn\left(NO_3\right)_2+2AgCl\)
b) \(m_{ZnCl_2}=\dfrac{200.13,6}{100}=27,2\left(g\right)\)
=> \(n_{ZnCl_2}=\dfrac{27,2}{136}=0,2\left(mol\right)\)
PTHH: ZnCl2 + 2AgNO3 --> Zn(NO3)2 + 2AgCl
0,2------>0,4--------->0,2-------->0,4
=> \(C\%\left(AgNO_3\right)=\dfrac{0,4.170}{200}.100\%=34\%\)
c)
mdd sau pư = 200 + 200 - 0,4.143,5 = 342,6(g)
=> \(C\%\left(Zn\left(NO_3\right)_2\right)=\dfrac{0,2.189}{342,6}.100\%=11,03\%\)