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1.\(n_{Zn}=\dfrac{13}{65}=0,2mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,2 ( mol )
\(V_{H_2}=0,2.22,4=4,48l\)
2.\(n_{CuO}=\dfrac{12}{80}=0,15mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,15 < 0,2 ( mol )
0,15 0,15 ( mol )
\(m_{Cu}=0,15.64=9,6g\)
\(a.n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ V_{H_2}=0,2.22,4=4,48\left(l\right)\\ b.n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\\ CuO+H_2-^{t^o}\rightarrow Cu+H_2O\\ LTL:\dfrac{0,15}{1}< \dfrac{0,2}{1}\\ \Rightarrow H_2dưsauphảnứng\\ n_{Cu}=n_{H_2\left(pứ\right)}=n_{H_2O}=n_{CuO}=0,15\left(mol\right)\\ m_{Cu}=0,15.64=9,6\left(g\right)\\ m_{H_2\left(dư\right)}=\left(0,2-0,15\right).2=0,1\left(g\right)\\ m_{H_2O}=0,15.18=2,7\left(g\right)\)
nZn = 13/65 = 0,2 (mol)
PTHH: Zn + 2HCl -> ZnCl2 + H2
Mol: 0,2 ---> 0,4 ---> 0,2 ---> 0,2
mZnCl2 = 0,2 . 136 = 27,2 (g)
VH2 = 0,2 . 22,4 = 4,48 (l)
nCuO = 12/80 = 0,15 (mol)
PTHH: CuO + H2 -> (t°) Cu + H2O
LTL: 0,15 < 0,2 => H2 dư
nCuO (p/ư) = nCu = nH2O = nCuO = 0,15 (mol)
mCu = 0,15 . 64 = 9,6 (g)
mH2O = 0,15 . 18 = 2,7 (g)
mCuO (dư) = (0,2 - 0,15) . 80 = 4 (g)
a.b.
\(n_{Fe}=\dfrac{2,8}{56}=0,05mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,05 0,1 0,05 ( mol )
\(V_{H_2}=0,05.22,4=1,12l\)
\(m_{HCl}=0,1.36,5=3,65g\)
c.
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,05 0,05 ( mol )
\(m_{Cu}=0,05.64=3,2g\)
a.\(n_{Zn}=\dfrac{m}{M}=\dfrac{23}{65}=0,35mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,35 0,35 ( mol )
\(V_{H_2}=n.22,4=0,35.22,4=7,84l\)
b.\(n_{CuO}=\dfrac{m}{M}=\dfrac{6}{80}=0,075mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,075 < 0,35 ( mol )
0,075 0,075 ( mol )
\(m_{Cu}=n.M=0,075.64=4,8g\)
`Mg + 2HCl -> MgCl_2 + H_2`
`0,15` `0,3` `0,15` `(mol)`
`n_[Mg]=[3,6]/24=0,15(mol)`
`a)V_[H_2]=0,15.22,4=3,36(l)`
`b)m_[HCl]=0,3.36,5=10,95(g)`
`c)`
`H_2 + CuO` $\xrightarrow{t^o}$ `Cu + H_2 O`
`0,15` `0,15` `(mol)`
`=>m_[Cu]=0,15.64=9,6(g)`
\(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\)
PTHH: Mg + 2HCl ---> MgCl2 + H2
0,15->0,3------------------>0,15
CuO + H2 --to--> Cu + H2O
0,15------>0,15
=> \(V_{H_2}=0,15.22,4=3,36\left(l\right)\\ m_{HCl}=0,3.36,5=10,95\left(g\right)\\ m_{Cu}=0,15.64=9,6\left(g\right)\)
a. \(Fe+2HCl\rightarrow FeCl_2+H_2\)
b. \(n_{Fe}=\dfrac{m_{Fe}}{M_{Fe}}=\dfrac{28}{56}=0,5\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,5-------1---------0,5-----0,5
Theo PTHH: \(\Rightarrow n_{H_2}=n_{Fe}=0,5\left(mol\right)\)
\(V_{H_2}=n_{H_2}.22,4=0,5.22,4=11,2\left(l\right)\)
c. \(H_2+CuO\rightarrow Cu+H_2O\)
0,5-------0,5-----0,5----0,5
\(\Rightarrow m_{Cu}=n_{Cu}.M_{Cu}=0,5.64=32\left(g\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, \(n_{Fe_2O_3}=\dfrac{6,4}{160}=0,04\left(mol\right)\)
PT: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,04}{1}< \dfrac{0,2}{3}\), ta được H2 dư.
Theo PT: \(n_{H_2\left(pư\right)}=3n_{Fe_2O_3}=0,12\left(mol\right)\Rightarrow n_{H_2\left(dư\right)}=0,2-0,12=0,08\left(mol\right)\)
\(\Rightarrow m_{H_2\left(dư\right)}=0,08.2=0,16\left(g\right)\)
Theo PT: \(n_{Fe}=2n_{Fe_2O_3}=0,08\left(mol\right)\Rightarrow m_{Fe}=0,08.56=4,48\left(g\right)\)
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
(mol).......0,3........0,6.........0,3.......0,3
a) \(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b) \(m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
c) \(200ml=0,2l\)
\(C_{M_{HCl}}=\dfrac{0,6}{0,2}=3\left(M\right)\)
d) \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
\(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ban đầu: 0,2......0,3
Phản ứng: 0,2....0,2.....0,2.....0,2
Dư:.....................0,1
Lập tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\left(0,2< 0,3\right)\)
\(\Rightarrow H_2\) dư