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\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
\(nO_2=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(\Rightarrow nP_2O_5=\dfrac{2}{5}nO_2=\dfrac{2}{5}.0,1=0,04\left(mol\right)\)
\(\Rightarrow mP_2O_5=0,04.\left(31.2+16.5\right)=5,68\left(g\right)\)
c/
pthh: \(2KMnO_4\rightarrow K_2MnO_4+MnO_2+O_2\uparrow\)
\(nO_2=0,1\left(mol\right)\)
\(\Rightarrow nKMnO_4=\dfrac{2}{1}.nO_2=\dfrac{2}{1}.0,1=0,2\left(mol\right)\)
\(\Rightarrow mKMnO_4=0,2.\left(39+55+16.4\right)=31,6\left(g\right)\)
a, \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
b, \(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\)
Theo PT: \(n_{P_2O_5}=\dfrac{1}{2}n_P=0,2\left(mol\right)\Rightarrow m_{P_2O_5}=0,2.142=28,4\left(g\right)\)
c, \(n_{O_2}=\dfrac{5}{4}n_P=0,5\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,5.22,4=11,2\left(l\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=\dfrac{1}{3}\left(mol\right)\Rightarrow m_{KClO_3}=\dfrac{1}{3}.122,5=\dfrac{245}{6}\left(g\right)\)
nFe = 16.8/56 = 0.3 (mol)
nO2 = 6.72/22.4 = 0.3 (mol)
2Fe + 3O2 -to-> Fe3O4
0.2___0.3________0.1
mFe dư = ( 0.3 - 0.2 ) * 56 = 5.6 (g)
mFe3O4 = 0.1*232 = 23.2 (g)
a)
3Fe+2O2→Fe3O4
b)
nFe=16,8/56=0,3mol
nO2=6,72/22,4=0,3mol
Ta có: 0,3/3<0,3/2=> O2 dư tính theo Fe
nFe3O4=0,3/3=0,1
mFe3O4=0,1.232=23,2g
a, PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{2}n_{O_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c, PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Có: O2 hao hụt 40% → H% = 100 - 40 = 60%
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,4\left(mol\right)\)
\(\Rightarrow n_{KMnO_4\left(TT\right)}=\dfrac{0,4}{60\%}=\dfrac{2}{3}\left(mol\right)\)
\(\Rightarrow m_{KMnO_4}=\dfrac{2}{3}.158\approx105,3\left(g\right)\)
a, PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{30}\left(mol\right)\Rightarrow m_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,733\left(g\right)\)
c, Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)
PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
\(n_{KMnO_4\left(LT\right)}=2n_{O_2}=\dfrac{2}{15}\left(mol\right)\)
\(\Rightarrow m_{KMnO_4\left(LT\right)}=\dfrac{2}{15}.158=\dfrac{316}{15}\left(g\right)\)
Mà: H% = 85%
\(\Rightarrow m_{KMnO_4\left(TT\right)}=\dfrac{\dfrac{316}{15}}{85\%}\approx24,78\left(g\right)\)
nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
a, Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PT: \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
Xét tỉ lệ: \(\dfrac{0,3}{2}< \dfrac{0,2}{1}\), ta được O2 dư.
Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{1}{2}n_{H_2}=0,15\left(mol\right)\)
\(\Rightarrow n_{O_2\left(dư\right)}=0,05\left(mol\right)\Rightarrow m_{O_2\left(dư\right)}=0,05.32=1,6\left(g\right)\)
b, \(n_{H_2O}=n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{H_2O}=0,3.18=5,4\left(g\right)\)
c, PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
_______0,3_______________________0,15 (mol)
\(\Rightarrow m_{KMnO_4}=0,3.158=47,4\left(g\right)\)
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