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a)\(n_{KMnO_4}=\dfrac{31,6}{158}=0,2\left(m\right)\)
\(PTHH:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
tỉ lệ :2 1 1 1
số mol :0,2 0,1 0,1 0,1
\(V_{O_2}=0,1.22,4=2,24\left(l\right)\)
b)\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(m\right)\)
\(PTHH:3Fe+2O_2\underrightarrow{ }Fe_3O_4\)
theo phương trình ta có tỉ lệ\(\dfrac{0,2}{3}>\dfrac{0,1}{2}\)=>Fe dư
\(PTHH:3Fe+2O_2\xrightarrow[]{}Fe_3O_4\)
tỉ lệ :3 2 1
số mol :0,15 0,1 0,05
\(m_{Fe_3O_4}=0,05.232=11,6\left(g\right)\)
\(n_{Zn}=\dfrac{m}{M}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
\(PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\)
1 2 1 1
0,05 0,1 0,05 0,05
a) \(V_{H_2}=n.24,79=0,05.24,79=1,2395\left(l\right)\)
\(m_{ZnCl_2}=n.M=0,05.\left(65+35,5.2\right)=6,8\left(g\right)\)
b) \(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ta cos tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\Rightarrow\) CuO dư.
Theo ptr, ta có: \(n_{Cu}=n_{H_2}=0,05mol\\ \Rightarrow m_{Cu}=n.M=0,05.64=3,2\left(g\right).\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Ta có: \(n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
THeo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,05\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,05.24,79=1,2395\left(l\right)\)
\(m_{ZnCl_2}=0,05.136=6,8\left(g\right)\)
b, Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\), ta được CuO dư.
Theo PT: \(n_{Cu}=n_{H_2}=0,05\left(mol\right)\Rightarrow m_{Cu}=0,05.64=3,2\left(g\right)\)
a.b.c.\(n_{Al}=\dfrac{2,7}{27}=0,1mol\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,1 0,1 0,15 ( mol )
\(V_{H_2}=0,15.22,4=3,36l\)
\(m_{AlCl_3}=0,1.133,5=13,35g\)
d.\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,15 0,1 ( mol )
\(m_{Fe}=0,1.56=5,6g\)
a) nFe=0,1(mol); nHCl=0,4(mol)
PTHH: Fe + 2 HCl -> FeCl2 + H2
Ta có: 0,1/1 < 0,4/2
=> Fe hết, HCl dư, tish theo nFe.
b) nH2=nFeCl2=Fe=0,1(mol)
=> V(H2,đktc)=0,1.22,4=2,24(l)
c) mFeCl2=127.0,1=12,7(g)
a) nFe=0,1(mol); nHCl=0,4(mol) PTHH: Fe + 2 HCl -> FeCl2 + H2 Ta có: 0,1/1 < 0,4/2 => Fe hết, HCl dư, tish theo nFe. b) nH2=nFeCl2=Fe=0,1(mol) => V(H2,đktc)=0,1.22,4=2,24(l) c) mFeCl2=127.0,1=12,7(g)
\(n_{Mg}=\frac{m}{M}=\frac{9,6}{24}=0,4mol\)
PTHH: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)
1 : 1 : 1 : 1 mol
0,4 0,4 0,4 0,4 mol
a. \(m_{MgSO_4}=n.M=0,4.\left(24+32+16.4\right)=48g\)
b. \(V_{H_2}=n.22,4=0,4.22,4=8,96l\)
c. \(n_{Fe_2O_3}=\frac{m}{M}=\frac{64}{56.2}+16.3=0,4mol\)
PTHH: \(3H_2+Fe_{2O_3}\rightarrow2Fe+3H_2O\left(ĐK:t^o\right)\)
3 : 1 : 2 : 3 mol
1, 7 0,4 0,8 1,2 mol
\(m_{Fe}=n.M=0,8.56=44,8g\)
`a)PTHH:`
`Fe + 2HCl -> FeCl_2 + H_2`
`0,3` `0,6` `0,3` `0,3` `(mol)`
`n_[Fe]=[22,4]/56=0,4(mol)`
`n_[HCl]=0,3.2=0,6(mol)`
Ta có:`[0,4]/1 > [0,6]/2`
`=>Fe` dư
`b)m_[FeCl_2]=0,3.127=38,1(g)`
`c)m_[Fe(dư)]=(0,4-0,3).56=5,6(g)`
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(n_{HCl}=0,3.2=0,6\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Xét: \(\dfrac{0,4}{1}>\dfrac{0,6}{2}\) ( mol )
0,3 0,6 0,3 ( mol )
\(m_{FeCl_2}=0,3.127=38,1\left(g\right)\)
\(m_{Fe\left(dư\right)}=\left(0,4-0,3\right).56=5,6\left(g\right)\)
a,\(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right);n_{H_2SO_4}=1,5.0,2=0,3\left(mol\right)\)
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: 0,3 0,3 0,3
Ta có: \(\dfrac{0,4}{1}>\dfrac{0,3}{1}\) ⇒ Mg dư, H2SO4 pứ hết
\(m_{MgSO_4}=0,3.120=36\left(g\right)\)
b,\(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
c, \(n_{Fe_2O_3}=\dfrac{6,4}{160}=0,04\left(mol\right)\)
PTHH: 3H2 + Fe2O3 → 2Fe + 3H2O
Mol: 0,04 0,08
Ta có: \(\dfrac{0,3}{3}>\dfrac{0,04}{1}\) ⇒ H2 dư, Fe2O3 pứ hết
\(\Rightarrow m_{Fe}=0,08.56=4,48\left(g\right)\)
\(b,n_{Fe}=\dfrac{50,4}{56}=0,9(mol)\\ PTHH:3Fe+2O_2\xrightarrow{t^o}Fe_3O_4\\ \Rightarrow n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3(mol)\\ \Rightarrow m_{Fe_3O_4}=0,3.232=69,6(g)\\ c,PTHH:Fe_3O_4+8HCl\xrightarrow{t^o}FeCl_2+2FeCl_3+4H_2O\\ \Rightarrow n_{FeCl_2}=0,3(mol);n_{FeCl_3}=0,6(mol)\\ \Rightarrow m_{\text {muối}}=m_{FeCl_2}+m_{FeCl_3}=0,3.127+0,6.162,5=135,6(g)\)