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a)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
_____0,1<---0,2<-------0,1<---0,1
=> mHCl = 0,2.36,5 = 7,3 (g)
=> \(m_{ddHCl}=\dfrac{7,3.100}{7,3}=100\left(g\right)\)
mdd sau pư = 0,1.24 + 100 - 0,1.2 = 102,2 (g)
\(C\%\left(MgCl_2\right)=\dfrac{0,1.95}{102,2}.100\%=9,2955\%\)
b)
CTHH: AaOb
PTHH: \(A_aO_b+2bHCl->aACl_{\dfrac{2b}{a}}+bH_2O\)
____________0,2------->\(\dfrac{0,1a}{b}\)
=> \(\dfrac{0,1a}{b}\left(M_A+35,5.\dfrac{2b}{a}\right)=13,5\)
=> \(M_A=\dfrac{64b}{a}=\dfrac{2b}{a}.32\)
Nếu \(\dfrac{2b}{a}=1\) => MA = 32 (L)
Nếu \(\dfrac{2b}{a}=2\) => MA = 64(Cu)
1.
a, \(n_{CO_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
PTHH: CO2 + 2NaOH → Na2CO3 + H2O
Mol: 0,05 0,1
b, \(C_{M_{ddNaOH}}=\dfrac{0,1}{0,1}=1M\)
2.
a, \(m_{HCl}=200.7,3\%=14,6\left(g\right)\Rightarrow n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
PTHH: CuO + 2HCl → CuCl2 + H2O
Mol: 0,2 0,4 0,2
b,\(m_{CuO}=0,2.80=16\left(g\right)\)
c, \(C\%_{ddCuCl_2}=\dfrac{0,2.135.100\%}{16+200}=12,5\%\)
\(n_{HCl}=\dfrac{200\cdot7.3\%}{36.5}=0.4\left(mol\right)\)
\(M+2HCl\rightarrow MCl_2+H_2\)
\(0.2.....0.4.........0.2........0.2\)
\(m_{MCl_2}=0.2\cdot\left(M+71\right)\left(g\right)\)
\(m_{dd}=0.2M+200-0.2\cdot2=0.2M+199.6\left(g\right)\)
\(C\%MCl_2=\dfrac{0.2\cdot\left(M+71\right)}{0.2M+199.6}\cdot100\%=12.05\%\)
\(\Rightarrow M=56\)
\(M:Sắt\)
\(n_{Fe}=\dfrac{19,6}{56}=0,35\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,35--> 0,7-----> 0,35--> 0,35
\(m_{dd.HCl}=\dfrac{0,7.36,5.100\%}{7,3\%}=350\left(g\right)\\ m_{dd}=19,6+350-0,35.2=368,9\left(g\right)\\ C\%_{FeCl_2}=\dfrac{127.0,35.100\%}{368,9}=12,05\%\)
\(n_{Fe2O3}=\dfrac{16}{160}=0,1\left(mol\right)\)
Pt : \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O|\)
1 6 2 3
0,1 0,6 0,2
a) \(n_{HCl}=\dfrac{0,1.6}{1}=0,6\left(mol\right)\)
\(m_{HCl}=0,6.36,5=21,9\left(g\right)\)
\(m_{ddHCl}=\dfrac{21,9.100}{7,3}=300\left(g\right)\)
b) \(n_{FeCl3}=\dfrac{0,6.2}{6}=0,2\left(mol\right)\)
⇒ \(m_{FeCl3}=0,2.162,5=32,5\left(g\right)\)
\(m_{ddspu}=16+300=316\left(g\right)\)
\(C_{FeCl3}=\dfrac{32,5.100}{316}=10,28\)0/0
PTHH: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(CuCl_2+2KOH\rightarrow2KCl+Cu\left(OH\right)_2\downarrow\)
a+b) Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
\(\Rightarrow n_{HCl}=0,2\left(mol\right)=n_{KOH}\) \(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2\cdot36,5}{300}\cdot100\%\approx2,43\%\\C_{M_{KOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\end{matrix}\right.\)
c) PTHH: \(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)
Theo các PTHH: \(n_{CuO\left(lý.thuyết\right)}=n_{Cu\left(OH\right)_2}=n_{Cu}=0,1\left(mol\right)\)
\(\Rightarrow n_{CuO}=0,1\cdot95\%=0,095\left(mol\right)\) \(\Rightarrow m_{CuO}=0,095\cdot80=7,6\left(g\right)\)
a) \(m_{HCl}=200.10,95\%=21,9\left(g\right)\)
b) \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
x_______2x________x____x(mol)
\(n_{HCl}=\dfrac{200.10,95\%}{36,5}=0,6\left(mol\right)\)
Dung dịch A phải có HCl dư mới có thể trung hòa được NaOH.
\(n_{NaOH}=0,05.2=0,1\left(mol\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
y________y______y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}2x+y=0,6\\y=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,25\\y=0,1\end{matrix}\right.\)
\(\Rightarrow a=m_{CaCO_3}=100x=100.0,25=25\left(g\right)\\ V=V_{CO_2\left(đktc\right)}=22,4x=22,4.0,25=5,6\left(l\right)\)
c)
\(m_{ddA}=25+200-0,25.44=214\left(g\right)\\ C\%_{ddCaCl_2}=\dfrac{0,25.111}{214}.100\approx12,967\%\\ C\%_{ddHCl\left(dư\right)}=\dfrac{0,1.36,5}{214}.100\approx1,706\%\)
1.
CuO + 2HCl \(\rightarrow\)CuCl2 + H2O
nCuO=\(\dfrac{16}{80}=0,2\left(mol\right)\)
mHCl=\(300.\dfrac{7,3}{100}=21,9\left(g\right)\)
nHCl=\(\dfrac{21,9}{36,5}=0,6\left(mol\right)\)
Vì 0,4<0,6 nên HCl dư 0,2(mol)
mHCl dư=0,2.36,5=7,3(g)
Theo PTHH ta có:
nCuO=nCuCl2=0,2(mol)
mCuCl2=0,2.135=27(g)
C% dd HCl=\(\dfrac{7,3}{300+16}.100\%=2,3\%\)
C% dd CuCl2 =\(\dfrac{27}{300+16}.100\%=8,54\%\)
NaOH + HCl \(\rightarrow\)NaCl + H2O
mHCl=\(200.\dfrac{7,3}{100}=14,6\left(g\right)\)
nHCl=\(\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
Theo PTHH ta có:
nNaOH=nHCl=nNaCl=0,4(mol)
mNaOH=0,4.40=16(g)
mNaCl=0,4.58,5=23,4(g)
C% NaCl=\(\dfrac{23,4}{200+16}.100\%=10,83\%\)