cho mạt sắt hoàn tan vào vừa đủ 100g dd h2s04 x%(vừa đủ) thu đc 224 ml khí đktc và dd X
A> Viết pthh
b> tính x
c> tính nồng độ % của dd muối tạo thành
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Ủa fen ơi, nFeCl2 sinh ra là 0,1 mol rồi còn tác dụng đủ sao được với Ba(OH)2 0,05 mol fen=)
\(n_{Fe}=a;n_{Cu}=b\\a. Fe+2HCl->FeCl_2+H_2\\ 2HCl+Ba\left(OH\right)_2->BaCl_2+2H_2O\\ b.m_{Fe}=56\cdot\dfrac{2,24}{22,4}=5,6g\\ \%m_{Fe}=\dfrac{5,6}{8,8}.100\%=63,64g\\ \%m_{Cu}=36,36\%\\ c.\sum n_{HCl}=0,2+2.0,1.0,5=0,3mol\\ x=\dfrac{0,3}{0,3}=1\left(M\right)\)
`1)`
`n_{Al}={2,7}/{27}=0,1(mol)`
`2Al+3H_2SO_4->Al_2(SO_4)_3+3H_2`
`0,1->0,15->0,05->0,15(mol)`
`V_{dd\ H_2SO_4}={0,15}/1=0,15(l)=150(ml)`
`->V=150`
`V'=V_{H_2}=0,15.22,4=3,36(l)`
`C_{M\ X}=C_{M\ Al_2(SO_4)_3}={0,05}/{0,15}=1/3M`
`2)`
`n_{Fe}={2,8}/{56}=0,05(mol)`
`Fe+2HCl->FeCl_2+H_2`
`0,05->0,1->0,05->0,05(mol)`
`V_{dd\ HCl}={0,1}/1=0,1(l)=100(ml)`
`->V=100`
`V_{H_2}=0,05.22,4=1,12(l)`
`C_{M\ FeCl_2}={0,05}/{0,1}=0,5M`
\(\text{Đặt }n_{Al}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 27x+56y=13,9(1)\\ n_{H_2}=\dfrac{7,84}{22,4}=0,35(mol)\\ a,PTHH:2Al+6HCl\to 2AlCl_3+3H_2(1)\\ Fe+2HCl\to FeCl_2+H_2(2)\\ b,\text{Từ 2 PT: }1,5x+y=0,35(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ \Rightarrow m_{Al}=0,1.27=2,7(g)\\ m_{Fe}=0,2.56=11,2(g)\)
\(c,n_{HCl(1)}=3n_{Al}=0,3(mol);n_{AlCl_3}=0,1(mol);n_{H_2(1)}=0,15(mol)\\ \Rightarrow m_{dd_{HCl(1)}}=\dfrac{0,3.36,5}{14,6\%}=75(g)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{0,1.133,5}{2,7+75-0,15.2}.100\%=17,25\%\)
\(n_{HCl(2)}=2n_{Fe}=0,4(mol);n_{FeCl_2}=n_{H_2(2)}=n_{Fe}=0,2(mol)\\ \Rightarrow m{dd_{HCl(2)}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%=22,92\%\)
a) 2Al + 6HCl --> 2AlCl3 + 3H2
Fe + 2HCl --> FeCl2 + H2
b) Gọi số mol Al, Fe lần lượt là a,b
=> 27a + 56b = 13,9
\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
2Al + 6HCl --> 2AlCl3 + 3H2
a----->3a--------->a------->1,5a______(mol)
Fe + 2HCl --> FeCl2 + H2
b------>2b-------->b----->b__________(mol)
=> 1,5a + b = 0,35
=> \(\left\{{}\begin{matrix}a=0,1=>m_{Al}=0,1.27=2,7\left(g\right)\\b=0,2=>m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
c) nHCl = 3a + 2b = 0,7 (mol)
=> mHCl = 0,7.36,5 = 25,55(g)
=> \(m_{ddHCl}=\dfrac{25,55.100}{14,6}=175\left(g\right)\)
\(m_{dd\left(saupu\right)}=13,9+175-2.0,35=188,2\left(g\right)\)
\(\left\{{}\begin{matrix}m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\m_{FeCl_2}=0,2.127=25,4\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{13,35}{188,2}.100\%=7,1\%\\C\%\left(FeCl_2\right)=\dfrac{25,4}{188,2}.100\%=13,5\%\end{matrix}\right.\)
a, PT: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,5.65=32,5\left(g\right)\)
\(\Rightarrow m_{CuO}=72,5-32,5=40\left(g\right)\)
c, Ta có: \(n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Zn}+n_{CuO}=1\left(mol\right)\)
\(\Rightarrow b=C_{M_{H_2SO_4}}=\dfrac{1}{2,5}=0,4M\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnSO_4}=n_{Zn}=0,5\left(mol\right)\\n_{CuSO_4}=n_{CuO}=0,5\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnSO_4}}=\dfrac{0,5}{2,5}=0,2M\\C_{M_{CuSO_4}}=\dfrac{0,5}{2,5}=0,2M\end{matrix}\right.\)
Bạn tham khảo nhé!
a, \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\left(I\right)\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\left(II\right)\)
b, Theo PTHH(1) : \(n_{Zn}=n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{Zn}=32,5\left(g\right)\)
\(\Rightarrow m_{CuO}=m_{hh}-m_{Zn}=40\left(g\right)\)
\(\Rightarrow n_{CuO}=\dfrac{m}{M}=0,5\left(mol\right)\)
c, Theo PTHH (1) và (2) : \(n_{H2SO4}=n_{CuO}+n_{Zn}=1\left(mol\right)\)
\(\Rightarrow C_{MH2SO4}=b=\dfrac{n}{V}=\dfrac{1}{2,5}=0,4M\)
d, ( Chắc là thể tích coi như không đổi )
Thấy sau phản ứng thu được A gồm \(0,5molZnSO_4,0,5molCuSO_4\)
\(\Rightarrow C_{MCuSO4}=C_{MZnSO4}=\dfrac{n}{V}=\dfrac{0,5}{2,5}=0,2M\)
Vậy ...
a) Fe + H2SO4 -----------> FeSO4 + H2
\(n_{Fe}=n_{H_2}=0,75\left(mol\right)\)
=> \(m_{Fe}=0,75.56=42\left(g\right)\)
b) \(CM_{H_2SO_4}=\dfrac{0,75}{0,25}=3M\)
c) \(m_{ddsaupu}=42+250.1,1-0,75.2=315,5\left(g\right)\)
=> \(C\%_{FeSO_4}=\dfrac{0,75.152}{315,5}.100=36,13\%\)
\(n_{SO_2}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)
\(PTHH:2Fe+6H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\)
Mol: 0,5 1,5 0,25 0,75 1,5
a)mFe=0,5.56=28 (g)
b)\(C_{MddH_2SO_4}=\dfrac{1,5}{0,25}=6\left(mol/l\right)\)
c)\(m_{Fe_2\left(SO_4\right)_3}=0,25.400=100\left(g\right)\)
\(m_{H_2O}=1,5.18=27\left(g\right)\)
\(C\%_{ddFe_2\left(SO_4\right)_3}=\dfrac{100.100}{100+27}=78,74\%\)
\(n_{Na_2SO_3}=\dfrac{12,6}{126}=0,1mol\)
\(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+SO_2+H_2O\)
a) \(n_{SO_2}=n_{Na_2SO_3}=0,1mol\) \(\Rightarrow V=2,24l\)
b) \(n_{H_2SO_4}=n_{Na_2SO_3}=0,1mol\) \(\Rightarrow C_M=\dfrac{0,1}{0,2}=0,5M\)
c) \(m_{Na_2SO_4}=0,1\cdot142=14,2g\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2-->0,4----->0,2------->0,2
a
\(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b
\(CM_{MgCl_2}=\dfrac{0,2}{0,2}=1M\)
c
\(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)
0,2------>0,4
\(V_{dd.NaOH}=\dfrac{0,4}{2}=0,2\left(l\right)\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PTHH :
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
0,2 0,4 0,2 0,2
\(a,V_{H_2}=0,2.22,4=4,48\left(l\right)\)
\(b,m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(m_{ddHCl}=\dfrac{14,6.100}{10}=146\left(g\right)\)
\(c,m_{MgCl_2}=0,2.95=19\left(g\right)\)
\(m_{ddMgCl_2}=4,8+146-\left(0,2.2\right)=150,4\left(g\right)\)
\(C\%_{MgCl_2}=\dfrac{19}{150,4}.100\%\approx12,63\%\)
2.
\(n_K=\dfrac{7,8}{39}=0,2\left(mol\right)\)
\(2K+2H_2O\rightarrow2KOH+H_2\uparrow\)
0,2 0,2 0,1
\(m_{KOH}=0,2.56=11,2\left(g\right)\)
\(m_{ddKOH}=7,8+100-\left(0,1.2\right)=107,6\left(g\right)\)
\(C\%=\dfrac{11,2}{107,6}.100\%\approx10,4\%\)
a) $Fe + H_2SO_4 \to FeSO_4 + H_2$
b)
Theo PTHH : $n_{H_2SO_4} = n_{H_2} = \dfrac{224}{1000.22,4} = 0,01(mol)$
$C\%_{H_2SO_4} = \dfrac{0,01.98}{100}.100\% = 0,98\%$
$\Rightarrow x = 0,98$
c) $n_{Fe} = n_{H_2} = 0,01(mol)$
$m_{dd\ sau\ pư} = m_{Fe} + m_{dd\ H_2SO_4} - m_{H_2} = 0,01.56 + 100 - 0,01.2 = 100,54(gam)$
$C\%_{FeSO_4} = \dfrac{0,01.152}{100,54}.100\% = 1,51\%$