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2Na+2H2O->2NaOH+H2
0,5-----0,5-----------0,5----0,25
Na2O+H2O->2NaOH
0,1--------0,1-----------0,2
n H2=0,25 mol
=>m Na =0,5.23=11,5g
=>m Na2O=6,2g=>n Na2O=0,1 mol
=>m NaOH=0,7.40=28g
=>VH2O=0,6.22,4=13,44l
\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)
$n_{Ba} = n_{Ba(OH)_2} = 0,12(mol)$
$n_{H_2} = \dfrac{1,12}{22,4} = 0,05(mol)$
Gọi $n_{Na} = a ; n_O = b$
Ta có :
$23a + 16b + 0,12.137 = 21,1$
Bảo toàn electron : $a + 0,12.2 = 2b + 0,05.2$
Suy ra $a = \dfrac{177}{1550} ; b = \dfrac{197}{1550}$
Suy ra $m_{NaOH} = \dfrac{177}{1550}.40 = 4,57(gam)$
a)
Gọi : \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\)⇒ 27a + 56b = 1,66(1)
\(2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe +2 HCl \to FeCl_2 + H_2\)
Theo PTHH :
\(n_{H_2} = 1,5a + b = \dfrac{1,12}{22,4} = 0,05(2)\)
Từ (1)(2) suy ra a = 0,02 ; b = 0,02
Vậy :
\(\%m_{Al} = \dfrac{0,02.27}{1,66}.100\% = 32,53\%\\ \%m_{Fe} = 100\% - 32,53\% = 67,47\%\)
a)
\(n_{HCl} = 2n_{H_2} = 0,05.2 = 0,1(mol)\\ \Rightarrow C\%_{HCl} = \dfrac{0,1.36,5}{100}.100\% = 3,65\%\)
a) nH2=0,05(mol)
Na + H2O -> NaOH + 1/2 H2
0,1_______________0,05(mol)
Na2O + H2O -> 2 NaOH
b) => mNa=0,1.23=2,3(g)
=>nNa2O= 14,7 - 2,3= 12,4(g)
PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\) (1)
\(Na_2O+H_2O\rightarrow2NaOH\) (2)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\) (3)
Ta có: \(\left\{{}\begin{matrix}n_{Na}=2n_{H_2\left(1\right)}=2\cdot\dfrac{2,24}{22,4}=0,2\left(mol\right)\\n_{Fe}=n_{H_2\left(3\right)}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Na}=\dfrac{0,2\cdot23}{16,4}\cdot100\%\approx28,05\%\\\%m_{Fe}=\dfrac{0,05\cdot56}{16,4}\cdot100\%\approx17,07\%\\\%m_{Na_2O}=54,88\%\end{matrix}\right.\)
a, \(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
PT: \(2Na+2H_2O\rightarrow2NaOH+H_2\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Theo PT: \(n_{Na}=2n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Na}=0,1.23=2,3\left(g\right)\)
\(\Rightarrow m_{Na_2O}=8,5-2,3=6,2\left(g\right)\)
b, \(n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
Theo PT: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=0,3\left(mol\right)\Rightarrow m_{NaOH}=0,3.40=12\left(g\right)\)