Đốt cháy hoàn toàn một lượng magie thu được 2,4g MgO a) viết phương trình phản ứng xảy ra b) tính thể tích o2 ở đktc cần dùng c) muốn có được thể tích oxi trên phải phân hủy bao nhiêu gam KClo3
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1. a. \(PTHH:2Mg+O_2\overset{t^o}{--->}2MgO\left(1\right)\)
b. Ta có: \(n_{Mg}=\dfrac{24}{24}=1\left(mol\right)\)
Theo PT(1): \(n_{O_2}=\dfrac{1}{2}.n_{Mg}=\dfrac{1}{2}.0,1=0,5\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,5.22,4=11,2\left(lít\right)\)
c. \(PTHH:2KClO_3\xrightarrow[t^o]{MnO_2}2KCl+3O_2\left(2\right)\)
Theo PT(2): \(n_{KClO_3}=\dfrac{2}{3}.n_{O_2}=\dfrac{2}{3}.0,5=\dfrac{1}{3}\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=\dfrac{1}{3}.122,5=40,83\left(g\right)\)
2. \(PTHH:3Fe+2O_2\overset{t^o}{--->}Fe_3O_4\)
Ta có: \(n_{Fe_3O_4}=\dfrac{2,32}{232}=0,01\left(mol\right)\)
a. Theo PT: \(n_{Fe}=3.n_{Fe_3O_4}=0,01.3=0,03\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,03.56=1,68\left(g\right)\)
b. Theo PT: \(n_{O_2}=2.n_{Fe_3O_4}=2.0,01=0,02\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,02.22,4=0,448\left(lít\right)\)
\(n_{Fe}=\dfrac{126}{56}=2,25\left(mol\right)\\
pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
2,25 1,5
=> \(V_{O_2}=1,5.22,4=33,6\left(L\right)\)
\(PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
1 1,5
=> \(m_{KClO3}=122,5\left(g\right)\)
a, \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
b, \(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{3}{4}n_{Al}=0,225\left(mol\right)\Rightarrow V_{O_2}=0,225.22,4=5,04\left(l\right)\)
c, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,15\left(mol\right)\Rightarrow m_{KClO_3}=0,15.122,5=18,375\left(g\right)\)
\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\ a,2Mg+O_2\rightarrow\left(t^o\right)2MgO\\ n_{O_2}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ V_{O_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\\ b,2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\\ n_{KClO_3}=\dfrac{0,05.2}{3}=\dfrac{1}{30}\left(mol\right)\\ \Rightarrow m_{KClO_3}=\dfrac{122,5}{30}=\dfrac{49}{12}\left(g\right)\)
\(n_P=\dfrac{7,44}{31}=0,24mol\)
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
0,24 0,3 0,12
\(V_{O_2}=0,3\cdot22,4=6,72l\)
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
0,2 0,3
\(m_{KClO_3}=0,2\cdot122,5=24,5g\)
3Fe+2O2-to>Fe3O4
0,225--0,15
n Fe=\(\dfrac{12,6}{56}\)=0,225 mol
VO2=0,15.22,4=3,36l
2KClO3-to>2KCl+3O2
0,1---------------------0,15
=>m KClO3=0,1.122,5=12,25g
\(a,3Fe+2O_2\rightarrow Fe_3O_4\)
\(b,\)
Ta có : \(n_{Fe}=\dfrac{m}{M}=\dfrac{126}{56}=2,25\left(mol\right)\)
\(\Rightarrow n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{2}{3}.2,25=1,5\left(mol\right)\)
\(\Rightarrow VO_2=33,6\left(l\right)\)
\(c,\)
\(PTHH:2KClO_3\rightarrow2KCl+3O_2\)
Theo \(PTHH:n_{KClO_3}=\dfrac{2}{3}n_{O_2}=\dfrac{2}{3}.1,5=1\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=n.M=1,122,5=122,5\left(g\right)\)
\(n_{Fe}=\dfrac{25,2}{56}=0,45\left(mol\right)\\ a,PTHH:3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\\ b,n_{O_2}=\dfrac{2}{3}.0,45=0,3\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ c,2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\\ n_{KClO_3}=\dfrac{2}{3}.0,3=0,2\left(mol\right)\\ \Rightarrow m_{KClO_3}=122,5.0,2=24,5\left(g\right)\)
mMg = 3.6/24 = 0.15 (mol)
2Mg + O2 -to-> 2MgO
0.15__0.075____0.15
mMgO= 0.15*40 = 6 (g)
VO2 = 0.075*22.4 = 1.68 (l)
2KClO3 -to-> 2KCl + 3O2
0.05_______________0.075
mKClO3 = 0.05*122.5 = 6.125 (g)
PTHH: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
a+b) Ta có: \(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{O_2}=0,075\left(mol\right)\\n_{MgO}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{O_2}=0,075\cdot22,4=1,68\left(l\right)\\m_{MgO}=0,15\cdot40=6\left(g\right)\end{matrix}\right.\)
c) PTHH: \(2KClO_3\xrightarrow[MnO_2]{t^o}2KCl+3O_2\uparrow\)
Theo PTHH: \(n_{KClO_3}=0,05\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=0,05\cdot122,5=6,125\left(g\right)\)
a, PT: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
b, Ta có: \(n_{MgO}=\dfrac{2,4}{40}=0,06\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{MgO}=0,03\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,03.22,4=0,672\left(l\right)\)
c, PT: \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,02\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=0,02.122,5=2,45\left(g\right)\)
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