Đốt cháy hoàn toàn 0,448 khí axetilen(đktc) A) Tính thể tích không khí cần dùng để đốt cháy hoàn toàn khi trên B) để hấp thụ hoàn toàn khí sinh ra sau phản ứng trên cần dùng bao nhiêu ml dung dịch Ca(OH)2 0,2 M?
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a.\(n_{CH_4}=\dfrac{V_{CH_4}}{22,4}=\dfrac{11,2}{22,4}=0,5mol\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
0,5 1 0,5 ( mol )
\(V_{kk}=V_{O_2}.5=\left(1.22,4\right).5=112l\)
b.\(n_{NaOH}=0,5.0,5=0,25mol\)
\(NaOH+CO_2\rightarrow NaHCO_3\)
0,25 < 0,5 ( mol )
0,25 0,25 ( mol )
\(m_{NaHCO_3}=0,25.84=21g\)
CH4+2O2-to>CO2+2H2O
0,5-----1----------0,5 mol
n CH4=\(\dfrac{11,2}{22,4}\)=0,5 mol
=>Vkk=1.22,4.5=112l
NaOH+CO2->NaHCO3
0,25------0,25-------0,25
n NaOH=0,5.0,5=0,25 mol
=>Tạo ra muối axit, CO2 dư
=>m NaHCO3=0,25.84=21g
a, PT: \(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
Ta có: \(n_{C_2H_4}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Theo PT: \(n_{O_2}=3n_{C_2H_4}=0,75\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,75.2,24=16,8\left(l\right)\)
\(\Rightarrow V_{kk}=16,8.5=84\left(l\right)\)
b, Theo PT: \(n_{CO_2}=2n_{C_2H_4}=0,5\left(mol\right)\)
PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{Ca\left(OH\right)_2}=n_{CaCO_3}=n_{CO_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{\downarrow}=m_{CaCO_3}=0,5.100=50\left(g\right)\)
\(m_{Ca\left(OH\right)_2}=0,5.74=37\left(g\right)\)
\(\Rightarrow m_{ddCa\left(OH\right)_2}=\dfrac{37.100}{2}=1850\left(g\right)\)
Bạn tham khảo nhé!
PTHH: 2C2H2 + 5O2 --to--> 4CO2 + 2H2O
\(\dfrac{V_{O_2}}{V_{C_2H_2}}=\dfrac{n_{O_2}}{n_{C_2H_2}}=\dfrac{5}{2}\Rightarrow V_{O_2}=2,5.\dfrac{5}{2}=6,25\left(l\right)\)
=> \(V_{kk}=6,25.5=31,25\left(l\right)\)
\(a.C_2H_5OH+3O_2-^{t^o}\rightarrow2CO_2+3H_2O\\ n_{C_2H_5OH}=0,3\left(mol\right)\\ n_{CO_2}=2n_{C_2H_5OH}=0,6\left(mol\right)\\ \Rightarrow V_{CO_2}=0,6.22,4=13,44\left(l\right)\\ b.n_{O_2}=3n_{C_2H_5OH}=0,6\left(mol\right)\\ MàV_{O_2}=\dfrac{1}{5}V_{kk}\\ \Rightarrow V_{kk}=V_{O_2}.5=0,6.22,4.5=67,2\left(l\right)\\ c.n_{NaOH}=0,9\left(mol\right)\\ Tacó:\dfrac{n_{NaOH}}{n_{CO_2}}=\dfrac{0,9}{0,6}=1,5\\ \Rightarrow Tạora2muốiNaHCO_3vàNa_2CO_3\\ Đặt:n_{NaHCO_3}=x\left(mol\right);n_{Na_2CO_3}=y\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}x+y=0,6\left(BTnguyento\left(C\right)\right)\\x+2y=0,9\left(BTnguyento\left(Na\right)\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=0,3\\y=0,3\end{matrix}\right.\\ \Rightarrow m_{muối}=0,3.84+0,3.106=57\left(g\right)\)
a, \(n_{CH_4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH:
CH4 + 2O2 --to--> CO2 + 2H2O
0,5--->1------------->0,5
Ca(OH)2 + CO2 ---> CaCO3 + H2O
0,5----->0,5
b, \(V_{O_2}=1.22,4=22,4\left(l\right)\)
c, \(m_{CaCO_3}=0,5.100=50\left(g\right)\)
\(n_C=\dfrac{14,4}{44}=\dfrac{18}{55}\left(mol\right)\\ C+O_2\rightarrow\left(t^o\right)CO_2\\ n_{O_2}=n_C=n_{CO_2}=\dfrac{18}{55}\left(mol\right)\\ a,V_{O_2\left(đktc\right)}=\dfrac{18}{55}.22,4=\dfrac{2016}{275}\left(lít\right)\\ b,V_{kk}=\dfrac{100}{21}.\dfrac{2016}{275}=\dfrac{381}{11}\left(lít\right)\\ c,2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\\ n_{KClO_3\left(LT\right)}=\dfrac{2}{3}.n_{O_2}=\dfrac{2}{3}.\dfrac{18}{55}=\dfrac{12}{55}\left(mol\right)\\ \Rightarrow n_{KClO_3\left(TT\right)}=120\%.\dfrac{12}{55}=\dfrac{72}{275}\left(mol\right)\\ \Rightarrow m_{KClO_3}=122,5.\dfrac{72}{275}=\dfrac{1764}{55}\left(g\right)\)
C2H2+5\2O2-to>2CO2+H2O
0,02--------0,05--------0,04
CO2+Ca(OH)2->CaCO3+H2O
0,04---------0,04
n C2H2=0,02 mol
=>Vkk=0,05.22,4.5=5,6l
VCa(OH)2=\(\dfrac{0,04}{0,2}\)=0,2l=200ml