Phân hủy x(g) KMnO4 thu được khí O2.Dùng lượng oxi trên đốt cháy hoàn toàn Cu thu được 16g CuO
a) Viết phương trình hóa học
b) Vo2 (đktc)
c) Tìm x(g)
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2KMnO4 ----to----> K2MnO4+MnO2 + O2
0,2 mol 0,1 mol
2Cu + O2 ---to---> 2CuO
0,2 0,1 0,2
n CuO=\(\frac{16}{80}\)=0,2(mol)
=>VO2=0,1.22,4=2,24(lít)
=>m KMnO4=0,2.158=31,6(g)
n H2O=\(\dfrac{3,6}{18}\)=0,2 mol
2H2O-đp->2H2+O2
0,2-------------------0,1 mol
2O2+3Fe-to>Fe3O4
0,1----------------0,05 mol
=>x=VO2=0,1.22,4=2,24l
=>y=m Fe3O4=0,05.232=11,6g
2KMnO4-to>K2MnO4+MnO2+O2
0,3-----------------0,15-----0,15------0,15 mol
n KMnO4=\(\dfrac{47,4}{158}\)=0,3 mol
=>mcr=0,15.197.0,15.87=42,6g
=>VO2=0,15.22,4=3,36l
b) 4P+5O2-to>2P2O5
0,1--------------0,05
nP=\(\dfrac{3,1}{31}\)=0,1 mol
->O2 dư
=>m P2O5=0,05.142=7,1g
mKMnO4 = 47,4/158 = 0,3 (mol)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2
Mol: 0,3 ---> 0,15 ---> 0,15 ---> 0,15
m = 0,15 . 197 + 0,15 . 87 = 85,2 (g)
V = VO2 = 0,15 . 22,4 = 3,36 (l)
nP = 3,1/31 = 0,1 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5
LTL: 0,1/4 < 0,15/5 => O2 dư
nP2O5 = 0,1/2 = 0,05 (mol)
mP2O5 = 0,05 . 142 = 7,1 (g)
a, \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
b, \(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{5}{4}n_P=0,25\left(mol\right)\Rightarrow V_{O_2}=0,25.22,4=5,6\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,5\left(mol\right)\Rightarrow m_{KMnO_4}=0,5.158=79\left(g\right)\)
\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\\ a,PTHH:4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\\ b,n_{O_2}=\dfrac{5}{4}.0,4=0,5\left(mol\right)\\ V_{O_2\left(đktc\right)}=0,5.22,4=11,2\left(l\right)\\ c,n_{P_2O_5}=\dfrac{2}{4}.0,4=0,2\left(mol\right)\\ m_{P_2O_5}=142.0,2=28,4\left(g\right)\)
a, PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Ta có: \(n_{KMnO_4}=\dfrac{31,6}{158}=0,2\left(mol\right)\)
Theo PT: \(n_{K_2MnO_4}=\dfrac{1}{2}n_{KMnO_4}=0,1\left(mol\right)\)
\(\Rightarrow m_{K_2MnO_4}=0,1.197=19,7\left(g\right)\)
b, Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{KMnO_4}=0,1\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,1.24,79=2,479\left(l\right)\)
c, PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
Theo PT: \(\left\{{}\begin{matrix}n_{CO_2}=\dfrac{1}{2}n_{O_2}=0,05\left(mol\right)\\n_{H_2O}=n_{O_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow V_{CO_2}=0,05.24,79=1,2395\left(l\right)\)
\(m_{H_2O}=0,1.18=1,8\left(g\right)\)
\(n_{Fe}=\dfrac{126}{56}=2,25\left(mol\right)\\
pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
2,25 1,5
=> \(V_{O_2}=1,5.22,4=33,6\left(L\right)\)
\(PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
1 1,5
=> \(m_{KClO3}=122,5\left(g\right)\)
a, PT: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
b, Ta có: \(n_{MgO}=\dfrac{2,4}{40}=0,06\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{MgO}=0,03\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,03.22,4=0,672\left(l\right)\)
c, PT: \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,02\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=0,02.122,5=2,45\left(g\right)\)
a, \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
b, \(n_{Al_2O_3}=\dfrac{20,4}{102}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{3}{2}n_{Al_2O_3}=0,3\left(mol\right)\Rightarrow V_{O_2}=0,3.22,4=6,72\left(l\right)\)
c, \(V_{kk}=\dfrac{V_{O_2}}{20\%}=33,6\left(l\right)\)
a)
2KMnO4 --to--> K2MnO4 + MnO2 + O2
2Cu + O2 --to--> 2CuO
b)
\(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
=> \(n_{O_2}=0,1\left(mol\right)\)
=> \(V_{O_2}=0,1.22,4=2,24\left(l\right)\)
c) \(n_{KMnO_4}=0,2\left(mol\right)\)
=> \(m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
2KMnO4-to>K2MnO4+MnO2+O2
0,2----------------------------------------0,1 mol
2Cu+O2-to>2CuO
0,2---0,1------0,2
n CuO=\(\dfrac{16}{80}\)=0,2 mol
=>VO2=0,1.22,4=2,24l
=>m KMnO4=0,2.158=31,6g