đốt cháy 6,8(g) bột sắt trong bình đựng V lít khí oxi (O2), sau phản ứng thu được oxit sắt từ (Fe3O4). Tính: a/ V (đo ở đktc ) đã tham gia phản ứng.
b/ Khối lượng (Fe3O4) thu được.
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a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
\(a/3Fe+2O_2\xrightarrow[]{t^0}Fe_3O_4\\ b/n_{Fe}=\dfrac{1,4}{56}=0,025mol\\ n_{O_2}=\dfrac{0,025.2}{3}=\dfrac{0,05}{3}mol\\ V_{O_2}=\dfrac{0,05}{3}\cdot22,4\approx0,37l\\ c/C_1\\ n_{Fe_3O_4}=\dfrac{0,025}{3}mol\\ m_{Fe_3O_4}=\dfrac{0,025}{3}\cdot232\approx1,93g\\ C_2\\ m_{O_2}=\dfrac{0,05}{3}\cdot32\approx0,53g\\ BTKL:m_{Fe}+m_{O_2}=m_{Fe_3O_4}\\ \Rightarrow m_{Fe_3O_4}=1,4+0,53=1,93g\)
a. \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
PTHH : 3Fe + 2O2 -to> Fe3O4
0,3 0,2 0,1
b. \(m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c. \(V_{O_2}=0,2.22,4=4,48\left(l\right)\)
a \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b \(\Rightarrow n_{Fe}=\dfrac{16,8}{56}=0,3mol\) \(\Rightarrow n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1mol\Rightarrow m_{Fe_3O_4}=0,1\cdot232=2,32g\)
c \(\Rightarrow n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2mol\Rightarrow V_{O_2}=0,2\cdot22,4=4,48l\)
a.b.\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,3 0,2 0,1 ( mol )
\(m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
\(V_{O_2}=0,2.22,4=4,48\left(l\right)\)
c. \(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,3 > 0,15 ( mol )
0,225 0,15 0,075 ( mol )
\(m_{Fe_3O_4}=0,075.232=17,4\left(g\right)\)
d. \(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
\(Fe_3O_4+4H_2\rightarrow\left(t^o\right)3Fe+4H_2O\)
0,075 < 0,35 ( mol )
0,075 0,3 ( mol )
Chất dư là H2
\(m_{H_2\left(dư\right)}=\left(0,35-0,3\right).2=0,1\left(g\right)\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1mol\)
Theo pt: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{2}{3}\cdot0,1=\dfrac{1}{15}mol\)
\(\Rightarrow V_{O_2}=\dfrac{1}{15}\cdot22,4=1,5l\)
Cũng theo pt: \(n_{Fe_3O_4}=\dfrac{1}{3}\cdot0,1=\dfrac{1}{30}mol\)
\(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{30}\cdot232=7,73g\)
\(a,BTKL:m_{Fe}+m_{O_2}=m_{Fe_3O_4}\\ \Rightarrow m_{O_2}=m_{Fe_3O_4}-m_{Fe}=23,2-16,8=6,4(g)\)
a)
Theo ĐLBTKL: \(m_{Fe\left(bđ\right)}+m_{O_2}=m_X\)
=> \(m_{O_2}=26,4-20=6,4\left(g\right)\)
=> \(n_{O_2}=\dfrac{6,4}{32}=0,2\left(mol\right)\Rightarrow V=0,2.22,4=4,48\left(l\right)\)
b)
PTHH: 3Fe + 2O2 --to--> Fe3O4
0,2------->0,1
=> \(\%m_{Fe_3O_4}=\dfrac{0,1.232}{26,4}.100\%=87,88\%\)
c)
- Nếu dùng KClO3
PTHH: 2KClO3 --to--> 2KCl + 3O2
\(\dfrac{0,4}{3}\)<-----------------0,2
=> \(m_{KClO_3}=\dfrac{0,4}{3}.122,5=\dfrac{49}{3}\left(g\right)\)
- Nếu dùng KMnO4:
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,4<--------------------------------0,2
=> \(m_{KMnO_4}=0,4.158=63,2\left(g\right)\)
\(n_{Fe}=\dfrac{6,8}{56}=0,12mol\)
3Fe + 2O2 \(\underrightarrow{t^o}\) Fe3O4
0,12 0,08 0,04 ( mol )
a, \(V_{O_2}=0,08.22,4=1,792l\)
b, mFe3O4 = 0,04.232 = 9,28g
\(n_{Fe}=\dfrac{6,8}{56}=\dfrac{17}{140}(mol)\\ PTHH:3Fe+2O_2\xrightarrow{t^o}Fe_3O_4\\ a,n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{17}{210}(mol)\\ \Rightarrow V_{O_2}=\dfrac{17}{210}.22,4=1,81(g)\\ b,n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{17}{420}(mol)\\ \Rightarrow m_{Fe_3O_4}=\dfrac{17}{420}.232=9,39(g)\)