cho 200ml dung dịch H3PO4 tác dụng hết với 300ml dung dịch ZnCl2 2Ma, Viết PTHH xảy ra
b, Tính khối lượng kết tủa thu đc
c, Tách bỏ kết tủa. Tính nồng độ M của dung dịch thu được
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\(n_{CuSO_4}=\dfrac{200.16\%}{160}=0,2\left(mol\right)\)
PTHH :
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)
0,2 0,4 0,2 0,2
\(m_{NaOH}=0,4.40=16\left(g\right)\)
\(m_{ddNaOH}=\dfrac{16.100}{10}=160\left(g\right)\)
\(c,m_{Na_2SO_4}=0,2.142=28,4\left(g\right)\)
\(m_{ddNa_2SO_4}=200+160-\left(0,2.98\right)=340,4\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{28,4}{240,4}.100\%\approx8,34\%\)
\(d,PTHH:\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
0,2 0,2
\(m_{CuO}=0,2.80=16\left(g\right)\)
a, \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
b, \(m_{CuSO_4}=200.16\%=32\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{32}{160}=0,2\left(mol\right)\)
\(n_{NaOH}=2n_{CuSO_4}=0,4\left(mol\right)\Rightarrow m_{ddNaOH}=\dfrac{0,4.40}{10\%}=160\left(g\right)\)
c, \(n_{Cu\left(OH\right)_2}=n_{Na_2SO_4}=n_{CuSO_4}=0,2\left(mol\right)\)
\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,2.142}{200+160-0,2.98}.100\%\approx8,34\%\)
d, \(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)
\(n_{Ca\left(OH\right)_2}=0,3\left(mol\right)\\ n_{H_3PO_4}=0,3\left(mol\right)\\ Vì:\dfrac{n_{Ca\left(OH\right)_2}}{n_{H_3PO_4}}=\dfrac{0,3}{0,3}=1\\ \Rightarrow Tạo.1.muối:CaHPO_4\\ Ca\left(OH\right)_2+H_3PO_4\rightarrow CaHPO_4+2H_2O\\ m_{\downarrow}=0\\ n_{CaHPO_4}=n_{Ca\left(OH\right)_2}=0,3\left(mol\right)\\ C_{MddCaHPO_4}=\dfrac{0,3}{0,3+0,3}=0,5\left(M\right)\)
a. PTHH: 3NaOH + AlCl3 ---> Al(OH)3↓ + 3NaCl (1)
Ta có: \(C_{\%_{NaOH}}=\dfrac{m_{NaOH}}{100}.100\%=12\%\)
=> mNaOH = 12(g)
=> \(n_{NaOH}=\dfrac{12}{40}=0,3\left(mol\right)\)
Ta lại có: \(C_{\%_{AlCl_3}}=\dfrac{m_{AlCl_3}}{200}.100\%=13,35\%\)
=> \(m_{AlCl_3}=26,7\left(g\right)\)
=> \(n_{AlCl_3}=\dfrac{26,7}{133,5}=0,2\left(mol\right)\)
Ta thấy: \(\dfrac{0,3}{3}< \dfrac{0,2}{1}\)
Vậy AlCl3 dư
Theo PT(1): \(n_{Al\left(OH\right)_3}=\dfrac{1}{3}.n_{NaOH}=\dfrac{1}{3}.0,3=0,1\left(mol\right)\)
=> \(m_{Al\left(OH\right)_3}=0,1.78=7,8\left(g\right)\)
b. Ta có: \(m_{dd_{NaCl}}=12+200-7,8=204,2\left(g\right)\)
Theo PT(1): \(n_{NaCl}=n_{NaOH}=0,3\left(mol\right)\)
=> \(m_{NaCl}=0,3.58,5=17,55\left(g\right)\)
=> \(C_{\%_{NaCl}}=\dfrac{17,55}{204,2}.100\%=8,59\%\)
c. PTHH: 2Al(OH)3 ---to---> Al2O3 + 3H2O (2)
Theo PT(2): \(n_{Al_2O_3}=\dfrac{1}{2}.n_{Al\left(OH\right)_3}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)
=> \(m_{Al_2O_3}=0,05.102=5,1\left(g\right)\)
PTHH: \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\downarrow\)
\(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CuCl_2}=0,2\cdot2=0,4\left(mol\right)\\n_{NaOH}=0,2\cdot2=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,4}{2}\) \(\Rightarrow\) CuCl2 còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{NaCl}=0,4\left(mol\right)\\n_{Cu\left(OH\right)_2}=0,2\left(mol\right)=n_{CuO}=n_{CuCl_2\left(dư\right)}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,2\cdot80=16\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,4}{0,2+0,2}=1\left(M\right)\\C_{M_{CuCl_2}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\\\end{matrix}\right.\)
\(n_{Na_2CO_3}=0,1.1=0,1\left(mol\right)\)
a. \(Na_2CO_3+Ba\left(OH\right)_2\rightarrow BaCO_3+2NaOH\)
0,1 0,1 0,1 0,2
b. \(m_{kt}=m_{BaCO_3}=0,1.197=19,7\left(g\right)\)
c. \(C\%_{Ba\left(OH\right)_2}=\dfrac{0,1.171.100}{200}=8,55\%\)
d. \(BaCO_3+2HCl\rightarrow BaCl_2+H_2O+CO_2\)
0,1 0,2
=> \(a=m_{dd.HCl}=\dfrac{0,2.36,5.100}{30}=\dfrac{73}{3}\left(g\right)\)
a.
\(Na_2CO_3+Ba\left(OH\right)_2\rightarrow BaCO_3+2NaOH\)
b.
\(n_{BaCO_3}=n_{Na_2CO_3}=0,2.1=0,2\left(mol\right)\\ m_{kt}=197.0,2=39,4\left(g\right)\)
c.
\(n_{Ba\left(OH\right)_2}=n_{Na_2CO_3}=0,2\left(mol\right)\\ C\%_{Ba\left(OH\right)_2}=\dfrac{0,2.171.100\%}{200}=17,1\%\)
PTHH 3ZnCl2+2H3PO4----->Zn3(PO4)2+6HCl
\(n_{ZnCl_2}\)=0,3.2=0,6(mol)
Theo phương trình =>\(\dfrac{1}{3}n_{ZnCl_2}=n_{Zn_3\left(PO_4\right)_2}=0,2\left(mol\right)\)
=>\(m_{Zn_3\left(PO_4\right)_2}\)=0,2.385=77(g)
Theo phương trình =>\(2n_{ZnCl_2}=n_{HCl}=1,2\left(mol\right)\)
=>\(C_{M_{HCl}}\)=\(\dfrac{1,2}{0,2+0,3}=2,4M\)