3. Để trung bình 100ml dung dich axit axetic cần 200ml dung dịch na tri hiđroxit 0,1M. tính nồng độ mol của ait axetic trog dung dich đã sử dụng.
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\(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\\ n_{NaOH}=0,2.0,1=0,02\left(mol\right)\\ n_{CH_3COOH}=n_{NaOH}=0,02\left(mol\right)\\ C_{MddCH_3COOH}=\dfrac{0,02}{0,1}=0,2\left(M\right)\)
\(n_{NaOH}=C_M\cdot V_{NaOH}=0,2\cdot0,1=0,02\left(mol\right)\)
PTHH:\(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
Theo PTHH: \(n_{CH_3COOH}=n_{NaOH}=0,02\left(mol\right)\)
Nồng độ mol của axit axetic là:
\(C_{M_{CH_3COOH}}=\dfrac{n_{CH_3COOH}}{V_{CH_3COOH}}=\dfrac{0,02}{0,1}=0,2\left(M\right)\)
\(n_{HCl}=0,2.0,2=0,04\left(mol\right)\)
Để trung hòa thì:
\(n_{NaOH}=n_{HCl}\)
\(\Leftrightarrow0,1.V_{NaOH}=0,04\)
\(\Leftrightarrow V_{NaOH}=0,4\left(l\right)=400\left(ml\right)\)
PTHH: \(HCl+NaOH\rightarrow NaCl+H_2O\)
\(\Rightarrow n_{NaCl}=n_{HCl}=0,04\left(mol\right)\)
\(V_{dd}=0,2+0,4=0,6\left(l\right)\)
\(\Rightarrow C_{M\left(NaCl\right)}=\dfrac{0,04}{0,6}=0,67M\)
2CH3COOH+Mg->(CH3COO)2Mg+H2
0,02---------------0,01-------0,01----------0,01
n muối=0,01mol
=>CM=\(\dfrac{0,02}{0,04}=0,5M\)
=>VH2=0,01.22,4=0,224l
CH3COOH+NaOH->CH3COONa+H2O
0,02--------------0,02
=>VNaOH=\(\dfrac{0,02}{0,75}=0,03l\)
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)
PTHH: Mg + 2CH3COOH --> (CH3COO)2Mg + H2
0,01<-------0,02<------------0,01------->0,01
=> \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,02}{0,04}=0,5M\)
b) VH2 = 0,01.22,4 = 0,224 (l)
c)
PTHH: NaOH + CH3COOH --> CH3COONa + H2O
0,02<------0,02
=> \(V_{dd.NaOH}=\dfrac{0,02}{0,75}=\dfrac{2}{75}\left(l\right)=\dfrac{80}{3}\left(ml\right)\)
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)
PTHH: Mg + 2CH3COOH --> (CH3COO)2Mg + H2
0,02<-----------0,01-------->0,01
=> VH2 = 0,01.22,4 = 0,224 (l)
\(C_{M\left(CH_3COOH\right)}=\dfrac{0,02}{0,2}=0,1M\)
b)
PTHH: CH3COOH + NaOH --> CH3COONa + H2O
0,02------>0,02
=> \(V_{dd.NaOH}=\dfrac{0,02}{0,2}=0,1\left(l\right)=100\left(ml\right)\)
$a\big)$
$n_{CH_3COOH}=\dfrac{100}{1000}.1=0,1(mol)$
$CH_3COOH+NaOH\to CH_3COONa+H_2O$
Theo PT: $n_{NaOH}=n_{CH_3COOH}=0,1(mol)$
$\to C\%_{NaOH}=\dfrac{0,1.40}{50}.100\%=80\%$
$b\big)$
$n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1(mol)$
$2CH_3COOH+Na_2CO_3\to 2CH_3COONa+CO_2+H_2O$
Theo PT: $\begin{cases} n_{CO_2}=n_{Na_2CO_3}=0,1(mol)\\ n_{CH_3COONa}=2n_{Na_2CO_3}=0,2(mol) \end{cases}$
$\to C\%_{CH_3COONa}=\dfrac{0,2.82}{60+10,6-0,1.44}.100\%\approx 24,77\%$
nKOH = 0,5.0,3 = 0,15 mol
CH3COOH + KOH → CH3COOK + H2O
0,15 0,15 0,15 mol
a) CM CH3COOH = 0,15/0,2 =0,75M
b) Thể tích của dung dịch thu được sau phản ứng: 500 ml
CM CH3COOK = 0,15/0,5 = 0,3M
c) Phản ứng lên men giấm
C2H5OH + O2 → CH3COOH + H2O
0,15 0,15
→ mC2H5OH = 0,15.46 = 6,9 gam
\(n_{KOH}=0,5\cdot0,3=0,15mol\)
\(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)
0,15 0,15 0,15 0,15
a)\(C_{M_{CH_3COOH}}=\dfrac{0,15}{0,2}=0,75M\)
b)\(C_{M_{CH_3COOK}}=\dfrac{0,15}{0,2+0,3}=0,3M\)
\(n_{NaOH}=0,2.1,5=0,3\left(mol\right)\)
PTHH: CH3COOH + NaOH ---> CH3COONa + H2O
0,1---------->0,1
=> mNaOH = 0,1.40 = 4 (g)
=> \(C\%_{NaOH}=\dfrac{4}{80}.100\%=5\%\)
PTHH: CH3COOH + C2H5OH --H2SO4(đặc), to--> CH3COOC2H5 + H2O
0,3------------------------------------------------>0,3
=> meste = 0,3.88.80% = 21,12 (g)