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\(n_{Fe}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,1 0,2 0,1
a) \(n_{Fe}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Fe}=0,1.56=5,6\left(g\right)\)
⇒ \(m_{Cu}=12-5,6=6,4\left(g\right)\)
b) \(n_{HCl}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
200ml = 0,2l
\(C_{M_{ddHCl}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
c) 0/0Fe = \(\dfrac{5,6.100}{12}=46,67\)0/0
0/0Cu = \(\dfrac{6,4.100}{12}=53,33\)0/0
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a) \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
mCu = mY = 9,6 (g)
Gọi số mol Al, Mg là a, b
=> 27a + 24b = 14,7 - 9,6 = 5,1 (g)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
a-->3a-------->a------>1,5a
Mg + 2HCl --> MgCl2 + H2
b--->2b------->b----->b
=> 1,5a + b = 0,25
=> a = 0,1; b = 0,1
=> \(\left\{{}\begin{matrix}m_{Al}=0,1.27=2,7\left(g\right)\\m_{Mg}=0,1.24=2,4\left(g\right)\\m_{Cu}=9,6\left(g\right)\end{matrix}\right.\)
b) nHCl(PTHH) = 3a + 2b = 0,5 (mol)
=> nHCl(thực tế) = \(\dfrac{0,5.120}{100}=0,6\left(mol\right)\)
=> \(C_{M\left(HCl\right)}=\dfrac{0,6}{0,2}=3M\)
c) \(\left\{{}\begin{matrix}C_{M\left(AlCl_3\right)}=\dfrac{0,1}{0,2}=0,5M\\C_{M\left(MgCl_2\right)}=\dfrac{0,1}{0,2}=0,5M\\C_{M\left(HCldư\right)}=\dfrac{0,6-0,5}{0,2}=0,5M\end{matrix}\right.\)
d) \(n_{Cu}=\dfrac{9,6}{64}=0,15\left(mol\right)\)
PTHH: \(Cu+Cl_2\underrightarrow{t^o}CuCl_2\)
0,15-->0,15
=> \(V_{Cl_2}=0,15.22,4=3,36\left(l\right)\)
\(a)Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\\ b)n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\ n_{Fe}=n_{H_2}=0,1mol\\ m_{Fe}=0,1.56=5,6g\\ m_{Fe_2O_3}=21,6-5,6=16g\\ c)n_{Fe_2O_3}=\dfrac{16}{160}=0,1mol\\ n_{H_2SO_4}=0,1+0,1.3=0,4mol\\ C_{M_{H_2SO_4}}=\dfrac{0,4}{0,5}=0,8M\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Fe}=b\left(mol\right)\left(a,b>0\right)\\n_{H_2}=\dfrac{2,16}{22,4}=0,09\left(mol\right)\\ \Rightarrow \left\{{}\begin{matrix}1,5a+b=0,09\\27a+56b=2,76\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,04\\b=0,03\end{matrix}\right.\\ \Rightarrow\%m_{Al}=\dfrac{0,04.27}{2,76}.100\approx39,13\%\\ \Rightarrow\%m_{Fe}\approx100\%-39,13\%\approx60,87\%\)
\(b,V_{ddsau}=V_{ddHCl}=0,2\left(l\right)\\ n_{AlCl_3}=n_{Al}=0,04\left(mol\right);n_{FeCl_2}=n_{Fe}=0,03\left(mol\right)\\ \Rightarrow C_{MddFeCl_2}=\dfrac{0,03}{0,2}=0,15\left(M\right)\\ C_{MddAlCl_3}=\dfrac{0,04}{0,2}=0,2\left(M\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
\(x\) \(1,5x\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
\(y\) \(y\)
Có \(27x+56y=2,76\left(1\right)\)
\(1,5x+y=\dfrac{2,016}{22,4}=0,09\left(2\right)\)
Từ (1) và (2)\(\Rightarrow\left\{{}\begin{matrix}x=0,04\\y=0,03\end{matrix}\right.\)
\(\%m_{Al}=\dfrac{0,04\cdot27}{2,76}\cdot100\%=39,13\%\)
\(\%m_{Fe}=100\%-39,13\%=60,87\%\)
Fe + 2HCl -> FeCl2 + H2
0.2 0.1
FeO + 2HCl -> FeCl2 + H2O
0.1 0.2
a.\(nH2=\dfrac{2.24}{22.4}=0.1mol\)
\(\%mFe=\dfrac{0.1\times56\times100}{12.8}=43.8\%\)
\(\%mFeO=100-43.8=56.2\%\)
b.\(nFeO=\dfrac{12.8-\left(0.1\times56\right)}{56+16}=0.1mol\)
\(V_{HCl}=\dfrac{0.2+0.2}{2}=0.2l\)
Vì Cu không tác dụng với HCl
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,1 0,2 0,1
a) \(n_{Fe}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Fe}=0,1.56=5,6\left(g\right)\)
\(m_{Cu}=12-5,6=6,4\left(g\right)\)
b) \(n_{HCl}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
200ml = 0,2l
\(C_{M_{ddHCl}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
c) 0/0Fe = \(\dfrac{5,6.100}{12}=46,67\)0/0
0/0Cu = \(\dfrac{6,4.100}{12}=53,33\)0/0
Chúc bạn học tốt
cảm mơn nhìu nhé