Hòa tan hoàn toàn 30 gam Calcium carbonate bằng 500 gam dung dịch hydrochloric acid nồng độ x M vừa đủ
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\(SO_3+H_2O\rightarrow H_2SO_4\\ H_2SO_4+Na_2SO_3\rightarrow Na_2SO_4+SO_2+H_2O\\ SO_2+Na_2O\rightarrow Na_2SO_3\\ Na_2SO_3+2HCl\rightarrow2NaCl+SO_2+H_2O\)
1, SO3+H2O->H2SO4
2, H2SO4+Na2SO3->Na2SO4+H2O+SO2
3, SO2+2NaOH->Na2SO3+H2O
4, Na2SO3+H2SO4->Na2SO4+H2O+SO2
a, \(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
Ta có: \(n_{Al_2O_3}=\dfrac{15,3}{102}=0,15\left(mol\right)\)
b, \(n_{AlCl_3}=2n_{Al_2O_3}=0,3\left(mol\right)\Rightarrow m_{AlCl_3}=0,3.133,5=40,05\left(g\right)\)
c, \(n_{HCl}=6n_{Al_2O_3}=0,9\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{0,9.36,5}{14,6\%}=225\left(g\right)\)
d, m dd sau pư = 15,3 + 225 = 240,3 (g)
\(\Rightarrow C\%_{AlCl_3}=\dfrac{40,05}{240,3}.100\%\approx16,67\%\)
e, nH2SO4 = 0,3.1 = 0,3 (mol)
PT: \(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{1}>\dfrac{0,3}{3}\), ta được Al2O3 dư.
→ Al2O3 không tan hết.
A: MgO, CuO
B: MgCl2, CuCl2
C: Mg(OH)2, Cu(OH)2
PT: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
\(2Cu+O_2\underrightarrow{t^o}2CuO\)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
\(n_{FeO}=\dfrac{2,16}{72}=0,03\left(mol\right)\\ n_{HCl}=0,2.0,4=0,08\left(mol\right)\\ a,PTHH:FeO+2HCl\rightarrow FeCl_2+H_2O\\ Vì:\dfrac{0,03}{1}< \dfrac{0,08}{2}\Rightarrow HCldư\\ n_{FeCl_2}=n_{FeO}=0,03\left(mol\right)\\ m_{FeCl_2}=127.0,03=3,81\left(g\right)\\ n_{HCl\left(Dư\right)}=0,08-2.0,03=0,02\left(mol\right)\\ V_{ddsau}=V_{ddHCl}=0,4\left(l\right)\\ C_{MddHCl\left(dư\right)}=\dfrac{0,02}{0,4}=0,05\left(M\right);C_{MddFeCl_2}=\dfrac{0,03}{0,4}=0,075\left(M\right)\)
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\\a, CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{H_2SO_4}=n_{CuO}=0,05\left(MOL\right)\\ b,m_{CuSO_4}=0,05.160=8\left(g\right)\\ c,V_{ddH_2SO_4}=\dfrac{0,05}{0,5}=0,1\left(l\right)\\ d,V_{ddCuSO_4}=V_{ddH_2SO_4}=0,1\left(l\right)\\ C_{MddCuSO_4}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
Nồng độ %? hoặc 500 ml dd HCl
\(n_{CaCO_3}=\dfrac{30}{100}=0,3mol\\ CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\\ n_{HCl}=0,3.2=0,6mol\\ \left[{}\begin{matrix}C_{M_{HCl}}\\C_{\%HCl}=\dfrac{0,6.36,5}{500}\cdot100=4,38\%\end{matrix}\right.=\dfrac{0,6}{0,5}=1,2M}\)