PT: \(CaCO_3\underrightarrow{t^o}CaO+CO_2\)

Theo ĐL BTKL, có: m_CaCO3 = m_CaO + m_CO2 = 44,8 + 35,2 = 80 (g)

\(\Rightarrow\%CaCO_3=\dfrac{80}{400}.100\%=20\%\) = x

\(\%Cu=\dfrac{64.100\%}{64+2\left(X+16.3\right)}=34,04\%\\ \Rightarrow X=14\)

X là Nito

Ta có: \(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\)

PT: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

____0,2__0,25_____0,1 (mol)

⇒ V_O2 = 0,25.24,79 = 6,1975 (l)

m_P2O5 = 0,1.142 = 14,2 (g)

Ta có: \(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\)

PT: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

____0,2__________0,1 (mol)

\(P_2O_5+3H_2O\rightarrow2H_3PO_4\)

0,1_________________0,2 (mol)

\(\Rightarrow C_{M_{H_3PO_4}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)

Ta có: \(m_{ddH_3PO_4}=400.1,15=460\left(g\right)\)

\(\Rightarrow C\%_{H_3PO_4}=\dfrac{0,2.98}{460}.100\%\approx4,26\%\)

Ta có: \(n_{H_2}+n_{O_2}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\) (1)

- Tỉ khối của X so với H₂ là 8,5.

\(\Rightarrow\dfrac{2n_{H_2}+32n_{O_2}}{n_{H_2}+n_{O_2}}=8,5.2\) \(\Rightarrow2n_{H_2}+32n_{O_2}=8,5.2.0,3\left(2\right)\)

Từ (1) và (2) ⇒ n_H2 = n_O2 = 0,15 (mol)

Gọi CTHH cần tìm là N_xO_y

Ta có: M_NxOy = 54.2 = 108 (g/mol)

\(\Rightarrow x=\dfrac{108.25,93\%}{14}=2\)

Mà: 14x + 16y = 108

⇒ y = 5

Vậy: CTHH cần tìm là N_xO₅.

a, CTHH: O₂

M_O2 = 16.2 = 32 (g/mol)

b, CTHH: CaCO₃

M_CaCO3 = 40 + 12 + 16.3 = 100 (g/mol)

c, CTHH: Fe₂O₃

M_Fe2O3 = 56.2 + 16.3 = 160 (g/mol)

d, CTHH: Al(OH)₃

M_Al(OH)3 = 27 + (16 + 1).3 = 78 (g/mol)

16

a, Gọi: n_Fe2O3 = n_CuO = a (mol)

⇒ 160a + 80a = 24 ⇒ a = 0,1 (mol)

PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)

Theo PT: \(n_{H_2SO_4}=n_{CuO}+3n_{Fe_2O_3}=0,4\left(mol\right)\)

\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,4}{0,5}=0,8\left(M\right)\)

b, Theo PT: \(\left\{{}\begin{matrix}n_{CuSO_4}=n_{CuO}=0,1\left(mol\right)\\n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,1\left(mol\right)\end{matrix}\right.\)

⇒ m _muối = m_CuSO4 + m_Fe2(SO4)3 = 0,1.160 + 0,1.400 = 56 (g)

c, \(C_{M_{CuSO_4}}=C_{M_{Fe_2\left(SO_4\right)_3}}=\dfrac{0,1}{0,5}=0,2\left(M\right)\)

a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

b, \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)

\(n_{HCl}=0,5.2,1=1,05\left(mol\right)\)

Theo PT: \(n_{HCl}=2n_{Zn}+3n_{Al}\Rightarrow n_{Zn}=0,225\left(mol\right)\)

⇒ m_Zn = 0,225.65 = 14,625 (g)

\(n_{H_2}=\dfrac{1}{2}n_{HCl}=0,525\left(mol\right)\Rightarrow V_{H_2}=0,525.24,79=13,01475\left(l\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,225\left(mol\right)\\n_{AlCl_3}=n_{Al}=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,225}{0,5}=0,45\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\end{matrix}\right.\)

đổi 1 tấn = 1000 kg

Pt CaCO₃ -> CaO + CO₂ 

Số mol CaCO₃ : 1000 : 100 = 1 mol 

=> nCaCO₃ = nCaO = nCO₂ 

Khối lượng CaO \(m=n.M.90\%=\dfrac{252}{5}\left(kg\right)\)

Thể tích CO₂ : \(V=n.22,4.90\%=20,16\left(l\right)\)